3-ETHOXY-2-CYCLOHEXEN-1-ONE
- CAS NO.：5323-87-5
- Empirical Formula: C8H12O2
- Molecular Weight: 140.18
- MDL number: MFCD00001580
- EINECS: 226-190-7
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-25 18:01:04
What is 3-ETHOXY-2-CYCLOHEXEN-1-ONE?
Chemical properties
Clear colorless to pale yellow liquid
The Uses of 3-ETHOXY-2-CYCLOHEXEN-1-ONE
3-Ethoxy-2-cyclohexen-1-one is a useful intermediate for the preparation of 3-alkyl- or aryl-2-cyclohexen-1-ones, by addition of organometallic reagents and subsequent hydrolysis. It helps in kinetic enolate formation (LDA) and alkylation occurs at the 6-position, the Stork-Danheiser kinetic alkylation procedure, which has found extensive use in alicyclic synthesis.
Properties of 3-ETHOXY-2-CYCLOHEXEN-1-ONE
| Boiling point: | 76-78 °C/1 mmHg (lit.) |
| Density | 0.963 g/mL at 25 °C (lit.) |
| refractive index | 1.503-1.505 |
| Flash point: | 107 °C |
| storage temp. | 2-8°C |
| form | Crystalline Powder |
| color | Off-white to peach |
| Water Solubility | Slightly soluble in water. |
| BRN | 2042049 |
| CAS DataBase Reference | 5323-87-5(CAS DataBase Reference) |
Safety information for 3-ETHOXY-2-CYCLOHEXEN-1-ONE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 3-ETHOXY-2-CYCLOHEXEN-1-ONE
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