3-BROMOCHLOROBENZENE
- CAS NO.:108-37-2
- Empirical Formula: C6H4BrCl
- Molecular Weight: 191.45
- MDL number: MFCD00000568
- EINECS: 203-575-8
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-09-09 19:09:56
What is 3-BROMOCHLOROBENZENE?
Chemical properties
CLEAR COLOURLESS TO LIGHT YELLOW LIQUID
The Uses of 3-BROMOCHLOROBENZENE
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
Synthesis Reference(s)
The Journal of Organic Chemistry, 52, p. 664, 1987 DOI: 10.1021/jo00380a031
General Description
1-Bromo-3-chlorobenzene undergoes bromine-magnesium exchange reactions with i-PrMgCl-LiCl in THF at 0°C and is strongly accelerated by electron-withdrawing substituents. It acts as test substrate to study the application of a new catalytic system for cyanation of various aryl halides using K4[Fe(CN)6] as cyanating source.
Properties of 3-BROMOCHLOROBENZENE
Melting point: | -21.5 °C |
Boiling point: | 196 °C(lit.) |
Density | 1.63 g/mL at 25 °C(lit.) |
refractive index | n |
Flash point: | 177 °F |
storage temp. | Sealed in dry,Room Temperature |
form | Liquid |
color | Clear colorless to light yellow |
Specific Gravity | 1.630 |
Water Solubility | Insoluble |
BRN | 1446353 |
Dielectric constant | 4.5 |
CAS DataBase Reference | 108-37-2(CAS DataBase Reference) |
NIST Chemistry Reference | 3-Chlorobromobenzene(108-37-2) |
EPA Substance Registry System | Benzene, 1-bromo-3-chloro- (108-37-2) |
Safety information for 3-BROMOCHLOROBENZENE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for 3-BROMOCHLOROBENZENE
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