3-Bromo-4-fluorobenzaldehyde
- CAS NO.:77771-02-9
- Empirical Formula: C7H4BrFO
- Molecular Weight: 203.01
- MDL number: MFCD00042186
- EINECS: 278-764-1
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-08-21 22:41:43
What is 3-Bromo-4-fluorobenzaldehyde?
Chemical properties
white to light yellow low melting solid
The Uses of 3-Bromo-4-fluorobenzaldehyde
3-Bromo-4-fluorobenzaldehyde can be used for pest control.
The Uses of 3-Bromo-4-fluorobenzaldehyde
3-Bromo-4-fluorobenzaldehyde was used in the synthesis of 4-fluoro-3-phenoxybenzoic acid-glycine. It was also used in the synthesis of Schiff bases of 4-nitroaniline/ 2,4-dinitroaniline/3,4-dichloroaniline/4-methoxy-3-nitro aniline via ultrasound irradiation method.
Synthesis
A synthetic method of 3-bromo-4-fluorobenzaldehyde comprises the following steps: (1) dissolving 4-fluorobenzaldehyde in dichloromethane to obtain a solution A; (2) dissolving sodium bromide in pure water and adding 35% hydrochloric acid while stirring to obtain a solution B; (3) mixing the solution A and the solution B, starting ultrasonic waves, and dropwise adding a sodium hypochlorite aqueous solution under stirring; (4) after the dripping is finished, carrying out ultrasonic treatment, keeping the temperature under stirring, and then standing; (5) phase separation, washing dichloromethane phase to neutrality, drying and desolventizing; (6) obtaining a crude product, and carrying out bulk melting crystallization at 31 ℃ to obtain a pure product.
Properties of 3-Bromo-4-fluorobenzaldehyde
Melting point: | 31-33 °C (lit.) |
Boiling point: | 138-139 °C/2.5 mmHg (lit.) |
Density | 1.6698 (rough estimate) |
refractive index | 1.574 |
Flash point: | >230 °F |
storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
form | Low Melting Solid |
color | White to light yellow |
Water Solubility | INSOLUBLE |
Sensitive | Air Sensitive |
BRN | 5806226 |
InChI | InChI=1S/C7H4BrFO/c8-6-3-5(4-10)1-2-7(6)9/h1-4H |
CAS DataBase Reference | 77771-02-9(CAS DataBase Reference) |
EPA Substance Registry System | Benzaldehyde, 3-bromo-4-fluoro- (77771-02-9) |
Safety information for 3-Bromo-4-fluorobenzaldehyde
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H302:Acute toxicity,oral H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
Precautionary Statement Codes |
P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 3-Bromo-4-fluorobenzaldehyde
InChIKey | FAHZIKXYYRGSHF-UHFFFAOYSA-N |
SMILES | C(=O)C1=CC=C(F)C(Br)=C1 |
Abamectin manufacturer
AATAMI Molecular Research Laboratories Pvt Ltd (AMRL)
BASR Fine Chemicals Pvt. Ltd.
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