2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine

CAS NO.：42573-57-9
Empirical Formula: C14H9Cl6N3O
Molecular Weight: 447.96
MDL number: MFCD01940892
EINECS: 255-893-1
SAFETY DATA SHEET (SDS)
Update Date: 2023-12-01 10:07:37

What is 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine?

The Uses of 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine

Cationic photoinitiator. Nonionic photoacid generator.

What are the applications of Application

2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine is a cationic photoinitiator and nonionic photoacid generator

Properties and Applications

2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine (R–Cl) appears as a versatile high-performance photoinitiator (PI) under LED exposure at 385, 395, or 405 nm (intensities in the range ～9–140 mW cm?2). It can be used as an efficient Type I cleavable photoinitiator for free radical polymerization of (meth)acrylates upon LED (e.g., 405 nm) exposure. Its high FRP photoinitiation ability under air demonstrates its capability to reduce the oxygen inhibition effect. Moreover, the R–Cl/amine (or R–Cl/N-vinylcarbazole) two-component system exhibits a higher photoinitiation ability than R–Cl alone in some cases. R–Cl/Iod/NVK is also efficient for the cationic photopolymerization of epoxides, especially at 405 nm[1].

References

[1] Zhang, Jing et al. “A known photoinitiator for a novel technology: 2-(4-methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine for near UV or visible LED?.” Polymer Chemistry 20 (2014): 6019–6026.

Properties of 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine

Melting point:	192-195 °C (lit.)
Boiling point:	511.4±60.0 °C(Predicted)
Density	1.605
form	powder to crystal
pka	-1.88±0.10(Predicted)
color	Light yellow to Amber to Dark green
InChI	InChI=1S/C14H9Cl6N3O/c1-24-9-5-2-8(3-6-9)4-7-10-21-11(13(15,16)17)23-12(22-10)14(18,19)20/h2-7H,1H3
EPA Substance Registry System	1,3,5-Triazine, 2-[2-(4-methoxyphenyl)ethenyl]-4,6-bis(trichloromethyl)- (42573-57-9)

Safety information for 2-(4-Methoxystyryl)-4,6-bis(trichloromethyl)-1,3,5-triazine

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.