(2-NAPHTHYL)METHYLZINC BROMIDE
- CAS NO.:152329-44-7
- Empirical Formula: C11H9BrZn
- Molecular Weight: 286.48
- MDL number: MFCD01311438
- SAFETY DATA SHEET (SDS)
What is (2-NAPHTHYL)METHYLZINC BROMIDE?
The Uses of (2-NAPHTHYL)METHYLZINC BROMIDE
(2-Naphthylmethyl)zinc bromide can be used as a reagent for the synthesis of:
- 4-(5,6-dimethoxy-2-(naphthalen-2-ylmethyl)pyridin-3-yl)benzonitrile from 4-(2-bromo-5,6-dimethoxypyridin-3-yl)benzonitrile using Pd catalyst.
- (E)-stilbene, (2,2′-[1,4-phenylenedi-(1E)-2,1-ethenediyl]bis[naphthalene]) from 1,4-benzenedicarboxaldehyde in the presence of Pd catalyst and a silylating agent.
General Description
(2-Naphthylmethyl)zinc bromide is an organozinc halide, which is typically used as a reagent in Negishi cross-coupling reactions. In this process, the organozinc halide reacts with organic halides or triflates to form a carbon-carbon bond in the presence of a Pd catalyst.
Properties of (2-NAPHTHYL)METHYLZINC BROMIDE
Density | 0.978 g/mL at 25 °C |
Flash point: | -17 °C |
storage temp. | 2-8°C |
Safety information for (2-NAPHTHYL)METHYLZINC BROMIDE
Signal word | Danger |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 Health Hazard GHS08 |
GHS Hazard Statements |
H225:Flammable liquids H302:Acute toxicity,oral H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H351:Carcinogenicity |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P370+P378:In case of fire: Use … for extinction. P403+P235:Store in a well-ventilated place. Keep cool. |
Computed Descriptors for (2-NAPHTHYL)METHYLZINC BROMIDE
New Products
4-Fluorophenylacetic acid 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate (6-METHYL-[1,3]DITHIOLO[4,5-b]QUINOXALIN-2-ONE INDAZOLE-3-CARBOXYLIC ACID 4-IODO BENZOIC ACID (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5,6-Dimethoxyindanone 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 2-aminopropyl benzoate hydrochloride 1-(4-(aminomethyl)benzyl)urea hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
3-BROMOBENZYLZINC BROMIDE
3,4-DIMETHOXYBENZYLZINC CHLORIDE
1-PENTYLZINC BROMIDE
2-THIAZOLYLZINC BROMIDE
4-METHOXYBENZYLZINC CHLORIDE
5-BROMO-2-METHOXYBENZYLZINC CHLORIDE
2 5-DIFLUOROBENZYLZINC CHLORIDE
2,6-DICHLOROBENZYLZINC CHLORIDE
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