2-METHYLPROPYLZINC BROMIDE
- CAS NO.：126403-67-6
- Empirical Formula: C4H9BrZn
- Molecular Weight: 202.4
- MDL number: MFCD00671802
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is 2-METHYLPROPYLZINC BROMIDE?
The Uses of 2-METHYLPROPYLZINC BROMIDE
Isobutylzinc bromide is an organozinc compound, which can be used as a reagent in the palladium-catalyzed Negishi cross-coupling reaction to construct a carbon-carbon bond by reacting with aryl or heteroaryl halides . It is also used to prepare regioselective unsaturated ketones by reacting with tert-butyl isocyanide via an allylic carbonylative coupling reaction in the presence of a nickel catalyst.
Properties of 2-METHYLPROPYLZINC BROMIDE
| Density | 0.943 g/mL at 25 °C |
| Flash point: | 1 °F |
| storage temp. | 2-8°C |
| Water Solubility | Reacts with water. |
| Sensitive | Air Sensitive |
Safety information for 2-METHYLPROPYLZINC BROMIDE
| Signal word | Danger |
| Pictogram(s) |
 Flame Flammables GHS02  Corrosion Corrosives GHS05  Exclamation Mark Irritant GHS07  Health Hazard GHS08 |
| GHS Hazard Statements |
H225:Flammable liquids H261:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases H302:Acute toxicity,oral H314:Skin corrosion/irritation H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H319:Serious eye damage/eye irritation H333:Acute toxicity,inhalation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation H351:Carcinogenicity |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P223:Keep away from any possible contact with water, because of violent reaction and possible flash fire. P280:Wear protective gloves/protective clothing/eye protection/face protection. P231+P232:Handle under inert gas. Protect from moisture. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P370+P378:In case of fire: Use … for extinction. P405:Store locked up. P402+P404:Store in a dry place. Store in a closed container. P403+P235:Store in a well-ventilated place. Keep cool. |
Computed Descriptors for 2-METHYLPROPYLZINC BROMIDE
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product: Isobutylzinc bromide 0.5 M in THF Cap: 100 ml 126403-67-6
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