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HomeProduct name list2-Methyl-3-(methylthio)pyrazine

2-Methyl-3-(methylthio)pyrazine

Synonym(s):Popcorn thiopyrazine

  • CAS NO.:2882-20-4
  • Empirical Formula: C6H8N2S
  • Molecular Weight: 140.21
  • MDL number: MFCD00014610
  • EINECS: 220-736-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-08-21 22:41:43
2-Methyl-3-(methylthio)pyrazine Structural

What is 2-Methyl-3-(methylthio)pyrazine?

Chemical properties

clear colorless liquid

Chemical properties

2-Methyl-3(or 5 or 6)-methylthiopyrazine has a roasted almond, hazelnut and vegetable aroma.

Preparation

From 2-methylchloropyrazine; a mixture of 2-methyl-3-methylthiopyrazine, 2-methyl-5-methylthiopyrazine, and 2-methyl-6-methylthiopyrazine is obtained.

Definition

ChEBI: 2-Methyl-(3 or 5 or 6)-(methylthio)pyrazine (mixture of isomers) is an aryl sulfide.

Aroma threshold values

Detection: 4 to 60 ppb. Aroma characteristics at 1.0%: toasted popcorn, roasted almond, hazelnut, peanut and cashewnutty, with a caramellic and corn-chip nuance.

Taste threshold values

Taste characteristics at 3 to 10 ppm: nutty, roasted and earthy with coffee and corn nuances, peanut and pecan nutty, popcorn and corn chip–like with a burnt musty nuance.

Properties of 2-Methyl-3-(methylthio)pyrazine

Boiling point: 213-214 °C (lit.)
Density  1.15 g/mL at 25 °C (lit.)
refractive index  n20/D 1.585(lit.)
FEMA  3208 | (METHYLTHIO)METHYLPYRAZINE (MIXTURE OF ISOMERS)
Flash point: 210 °F
storage temp.  Sealed in dry,Room Temperature
form  clear liquid
pka 0.88±0.10(Predicted)
color  Colorless to Almost colorless
Odor at 0.10 % in propylene glycol. roasted meat nutty almond vegetable
JECFA Number 797
CAS DataBase Reference 2882-20-4(CAS DataBase Reference)
NIST Chemistry Reference Pyrazine, 2-methyl-3-(methylthio)-(2882-20-4)
EPA Substance Registry System Pyrazine, 2-methyl-3-(methylthio)- (2882-20-4)

Safety information for 2-Methyl-3-(methylthio)pyrazine

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P271:Use only outdoors or in a well-ventilated area.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 2-Methyl-3-(methylthio)pyrazine

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