2-HYDROXY-1,3,5-BENZENETRICARBALDEHYDE
- CAS NO.：81502-74-1
- Empirical Formula: C9H6O4
- Molecular Weight: 178.14
- MDL number: MFCD01314207
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-06-03 14:14:04
What is 2-HYDROXY-1,3,5-BENZENETRICARBALDEHYDE?
Chemical properties
2-Hydroxy- 1,3,5-benzenetricarbaldehyde has a very limited solubility in most organic solvents and in water. It dissolves well in DMSO and in hot DMF, and the latter can be used as a recrystallization solvent. While the trialdehyde 3 is colorless in its free acid form, its anion absorbs light in the visible region giving the compound a yellow coloration in solutions when dissociation can occur. The yellow sodium salt of 2-hydroxy- 1,3,5-benzenetricarbaldehyde is only slightly soluble in water.
Synthesis
2-Hydroxybenzene-1,3,5-tricarbaldehyde is synthesized from phenol or 4-hydroxybenzaldehyde[1].
References
[1] A. ANDERSON. A Convenient One-Step Synthesis of 2-Hydroxy-1,3,5-Benzenetricarbaldehyde[J]. Synthetic Communications, 2000. DOI:10.1080/00397910008086933.
Properties of 2-HYDROXY-1,3,5-BENZENETRICARBALDEHYDE
| Melting point: | 179 °C |
| Boiling point: | 282.9±40.0 °C(Predicted) |
| Density | 1.449±0.06 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| form | powder to crystal |
| pka | 4.20±0.23(Predicted) |
| color | White to Yellow |
| λmax | 335nm(EtOH)(lit.) |
Safety information for 2-HYDROXY-1,3,5-BENZENETRICARBALDEHYDE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation |
| Precautionary Statement Codes |
P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. P332+P313:IF SKIN irritation occurs: Get medical advice/attention. P337+P313:IF eye irritation persists: Get medical advice/attention. |
Computed Descriptors for 2-HYDROXY-1,3,5-BENZENETRICARBALDEHYDE
New Products
4-Fluorophenylacetic acid 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL Tert-butyl bis(2-chloroethyl)carbamate 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid S-2-CHLORO PROPIONIC ACID ETHYL ISOCYANOACETATE 2-Bromo-1,3-Bis(Dimethylamino)Trimethinium Hexafluorophosphate (6-METHYL-[1,3]DITHIOLO[4,5-b]QUINOXALIN-2-ONE INDAZOLE-3-CARBOXYLIC ACID 4-IODO BENZOIC ACID (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5,6-Dimethoxyindanone 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 2-aminopropyl benzoate hydrochloride 1-(4-(aminomethyl)benzyl)urea hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
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