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HomeProduct name list1H,1H,2H,2H-Heptadecafluorodecyl acrylate

1H,1H,2H,2H-Heptadecafluorodecyl acrylate

Synonym(s):1H,1H,2H,2H-Perfluorodecyl acrylate;3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,10-Heptadecafluorodecyl acrylate

  • CAS NO.:27905-45-9
  • Empirical Formula: C13H7F17O2
  • Molecular Weight: 518.17
  • MDL number: MFCD00042306
  • EINECS: 248-722-7
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2024-10-28 16:48:35
1H,1H,2H,2H-Heptadecafluorodecyl acrylate Structural

What is 1H,1H,2H,2H-Heptadecafluorodecyl acrylate?

Chemical properties

clear colorless liquid

The Uses of 1H,1H,2H,2H-Heptadecafluorodecyl acrylate

(Perfluorooctyl)ethyl Acrylate is a reagent used in the synthesis of parahydrophobic polymer coatings, as well as polymer brushes for controlling surface lubrication.

Definition

1H,1H,2H,2H-Heptadecafluorodecyl acrylate is a semi-volatile fluorinated organic compound and is in polluted air in Asia and the western United States during the spring. The structure of this substance contains multiple fluorine atoms and a terminal olefin unit. It has high chemical reactivity and is sensitive to intense light. Perfluorooctylethyl acrylate contains an unsaturated double-bond unit and can be used to prepare perfluoroacrylate polymers.

What are the applications of Application

1H,1H,2H,2H-Heptadecafluorodecyl acrylate can be applied as follows:
(1) Coatings Industry: Due to their low surface tension and excellent heat resistance, 1H,1H,2H,2H-Heptadecafluorodecyl acrylate are commonly used in the preparation of high-performance surface coatings, such as water-repellent, oil-repellent, corrosion-repellent, anti-adhesive and temperature-resistant coatings[1-2].
(2) Lubricants: It can be used as a lubricant, especially where oil and water resistance is required.
(3) Surface Modifiers: In surface modification of textiles, plastics and other materials, it can provide special surface properties such as anti-staining and anti-adhesion[3].
(4) Electronic encapsulation material: Due to its chemical inertness and heat resistance, it can also be used as encapsulation material for electronic products, such as liquid crystal displays and fibre optic manufacturing.

Research

Latex based upon fluorinated acrylates such as perfluorooctylethyl methacrylate (FMA) and perfluorooctylethyl acrylate (FA; 1H,1H,2H,2H-Heptadecafluorodecyl acrylate) and fluorine-free acrylates such as n-butyl methacrylate (BMA) was prepared using emulsion polymerization in the presence of octadecyltrimethylammonium bromide (C18TAB) and 2,2′-azobis(2-amidinopropane) dihydrochloride (V50) as water-soluble azo initiator[4].

References

[1] VIRENDRA KUMAR. Fluorocarbon Coatings Via Plasma Enhanced Chemical Vapor Deposition of 1H,1H,2H,2H‐perfluorodecyl Acrylate ‐ 2, Morphology, Wettability and Antifouling Characterization[J]. Plasma Processes and Polymers, 2010. DOI:10.1002/PPAP.201000038.
[2] N. YOSHINO. Syntheses and Reactions of Metal Organics. XVII. Synthesis of Silane Coupling Agent Having Fluorocarbon Chain and Surface Modification of Glass Plate[J]. Bulletin of the Chemical Society of Japan, 1993. DOI:10.1246/BCSJ.66.472.
[3] JIYOUNG LEE . Robust and superomniphobic core-shell SiO2@poly(1H,1H,2H,2H-heptadecafluorodecyl methacrylate-co-methyl methacrylate) coating materials synthesized by thiol lactam initiated radical polymerization[J]. Progress in Organic Coatings, 2020. DOI:10.1016/j.porgcoat.2020.105851.
[4] Reinhard F. Linemann. “Latex Blends of Fluorinated and Fluorine-Free Acrylates: Emulsion Polymerization and Tapping Mode Atomic Force Microscopy of Film Formation.” Macromolecules 32 6 (1999): 1715–1721.

Properties of 1H,1H,2H,2H-Heptadecafluorodecyl acrylate

Melting point: -3°C
Boiling point: 90 °C4 mm Hg(lit.)
Density  1.637 g/mL at 25 °C(lit.)
refractive index  n20/D 1.337(lit.)
Flash point: >230 °F
storage temp.  2-8°C
solubility  Chloroform, Methanol (Slightly), Water (Sparingly)
form  Liquid
color  Clear colorless
Specific Gravity 1.596
BRN  5173337
Stability: Light Sensitive
CAS DataBase Reference 27905-45-9(CAS DataBase Reference)
EPA Substance Registry System 1,1,2,2-Tetrahydroperfluorodecyl acrylate (27905-45-9)

Safety information for 1H,1H,2H,2H-Heptadecafluorodecyl acrylate

Signal word Danger
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
ghs
Health Hazard
GHS08
GHS Hazard Statements H351:Carcinogenicity
H362:Reproductive toxicity, effects on or via lactation
H372:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P202:Do not handle until all safety precautions have been read and understood.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P263:Avoid contact during pregnancy/while nursing.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P308+P313:IF exposed or concerned: Get medical advice/attention.

Computed Descriptors for 1H,1H,2H,2H-Heptadecafluorodecyl acrylate

InChIKey QUKRIOLKOHUUBM-UHFFFAOYSA-N

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