1,3-Diiminoisoindoline

Synonym(s):1,3-Isoindolinediimine;Phthalimide diimide

CAS NO.：3468-11-9
Empirical Formula: C8H7N3
Molecular Weight: 145.16
MDL number: MFCD00010062
EINECS: 222-426-8
SAFETY DATA SHEET (SDS)
Update Date: 2024-08-01 17:24:36

What is 1,3-Diiminoisoindoline?

Chemical properties

Off yellow crystals

The Uses of 1,3-Diiminoisoindoline

1,3-Diiminoisoindoline is a useful compound in the production of colouring compositions. Dyes and metabolites.

What are the applications of Application

1,3-Diiminoisoindoline is a dye used to synthesize symmetrical complexes

Flammability and Explosibility

Not classified

Safety Profile

A severe eye and skin irritant. Questionable carcinogen with experimental carcinogenic and tumorigenic data. When heated to decomposition it emits toxic fumes of Nox

Purification Methods

It crystallises from H2O, MeOH or MeOH/Et2O (charcoal) in colourless prisms that become green on heating. [Elvidge & Linstead J Chem Soc 5000 1952]. IR (nujol): 3150 and 690 cm-1 , and UV: max 251nm ( 12,500), 256nm ( 12,5000) and 303nm ( 4,600) [Elvidge & Golden J Chem Soc 700 1957, Clark et al. J Chem Soc 3593 1953]. The thiocyanate has m 250-255o (dec), the monohydrochloride has m 300-301o (turns green), and the dihydrochloride has m 326-328o (turns green) and the picrate crystallises from EtOH with m 299o (dec). [Beilstein 22/13 V 5.]

Properties of 1,3-Diiminoisoindoline

Melting point:	~197 °C (dec.)(lit.)
Boiling point:	254.27°C (rough estimate)
Density	1.2109 (rough estimate)
vapor pressure	0.003Pa at 20℃
refractive index	1.5400 (estimate)
storage temp.	-20°C Freezer, Under inert atmosphere
solubility	DMSO (Slightly, Sonicated), Methanol (Slightly)
form	Solid
pka	8.47±0.20(Predicted)
color	Pale Yellow
Water Solubility	31.6g/L at 20℃
BRN	118477
CAS DataBase Reference	3468-11-9(CAS DataBase Reference)
EPA Substance Registry System	1H-Isoindol-3-amine, 1-imino- (3468-11-9)

Safety information for 1,3-Diiminoisoindoline

Signal word	Danger
Pictogram(s)	Corrosion Corrosives GHS05 Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.