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HomeProduct name list1,2-BIS(DIPHENYLPHOSPHINO)BENZENE

1,2-BIS(DIPHENYLPHOSPHINO)BENZENE

Synonym(s):dppBz;dppbe;dppbenz;1,2-Bis(diphenylphosphanyl)benzene;dppben

1,2-BIS(DIPHENYLPHOSPHINO)BENZENE Structural

What is 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE?

Chemical properties

white to light yellow crystal powde

The Uses of 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE

1,2-Bis(diphenylphosphino)benzene (DPPB) can be used:

  • As a chelating ligand in the synthesis of luminescent copper(I) halide complexes.
  • In the synthesis of copper-1,2-bis(diphenylphosphino)benzene catalyst which is used for the β-boration of α, β-unsaturated amide.
  • As an alternative to TMEDA for the selective cleavage of sp3 C-X bond in fluoroaromatic coupling reactions catalyzed by iron.
  • As a ligand in the synthesis of alkenylboronates from acetylenic esters.
  • To synthesize copper-diphosphine complexes which are used as homogeneous catalysts for N-formylation of a wide range of amines.

Properties of 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE

Melting point: 183-188 °C (lit.)
Boiling point: 546.9±33.0 °C(Predicted)
storage temp.  Inert atmosphere,Room Temperature
form  Fine Crystalline Powder
color  White
Water Solubility  Insoluble in water.
Sensitive  Air Sensitive
CAS DataBase Reference 13991-08-7(CAS DataBase Reference)

Safety information for 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE

InChIKey NFRYVRNCDXULEX-UHFFFAOYSA-N

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