1,2-BIS(DIPHENYLPHOSPHINO)BENZENE
Synonym(s):dppBz;dppbe;dppbenz;1,2-Bis(diphenylphosphanyl)benzene;dppben
- CAS NO.：13991-08-7
- Empirical Formula: C30H24P2
- Molecular Weight: 446.47
- MDL number: MFCD00014081
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-11 17:26:00
What is 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE?
Chemical properties
white to light yellow crystal powde
The Uses of 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE
1,2-Bis(diphenylphosphino)benzene (DPPB) can be used:
- As a chelating ligand in the synthesis of luminescent copper(I) halide complexes.
- In the synthesis of copper-1,2-bis(diphenylphosphino)benzene catalyst which is used for the β-boration of α, β-unsaturated amide.
- As an alternative to TMEDA for the selective cleavage of sp3 C-X bond in fluoroaromatic coupling reactions catalyzed by iron.
- As a ligand in the synthesis of alkenylboronates from acetylenic esters.
- To synthesize copper-diphosphine complexes which are used as homogeneous catalysts for N-formylation of a wide range of amines.
Properties of 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE
| Melting point: | 183-188 °C (lit.) |
| Boiling point: | 546.9±33.0 °C(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Fine Crystalline Powder |
| color | White |
| Water Solubility | Insoluble in water. |
| Sensitive | Air Sensitive |
| CAS DataBase Reference | 13991-08-7(CAS DataBase Reference) |
Safety information for 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H315:Skin corrosion/irritation H319:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation |
| Precautionary Statement Codes |
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1,2-BIS(DIPHENYLPHOSPHINO)BENZENE
| InChIKey | NFRYVRNCDXULEX-UHFFFAOYSA-N |
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