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Home Product name list(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

Synonym(s):(R)-3,3′-Bis(9-phenanthryl)-1,1′-binaphthalene-2,2′-diyl hydrogen phosphate

CAS NO.：864943-22-6
Empirical Formula: C48H29O4P
Molecular Weight: 700.72
MDL number: MFCD12546016
SAFETY DATA SHEET (SDS)
Update Date: 2022-12-30 16:20:48

(11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide Structural

What is (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide?

The Uses of (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

Catalyst for:

Asymmetric hydrogenation cascade
Enantioselective Friedel-Crafts reaction
Asymmetric hydrogenation of 2-substituted quinolines
Chiral Broensted acid catalyzed enantioselective a-aminoxylation of ene carbamates
Preparation of β-carbolines via diastereo- and enantioselective N-acyliminium cyclization cascades of tryptamines and keto acids/esters
Asymmetric transfer hydrogenation of substituted quinoxalines

Properties of (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

Melting point:	390-400°C
Density	1.46±0.1 g/cm3(Predicted)
storage temp.	-20°C
pka	1.11±0.20(Predicted)
optical activity	[α]22/D 44.0°, c = 1 in DMSO
CAS DataBase Reference	864943-22-6

Safety information for (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

Signal word	Warning
Pictogram(s)	Exclamation Mark Irritant GHS07
GHS Hazard Statements	H315:Skin corrosion/irritation
Precautionary Statement Codes	P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P280:Wear protective gloves/protective clothing/eye protection/face protection. P302+P352:IF ON SKIN: wash with plenty of soap and water. P332+P313:IF SKIN irritation occurs: Get medical advice/attention.

Computed Descriptors for (11bR)-2,6-Di-9-phenanthrenyl-4-hydroxy-dinaphtho[2,1-d:1′,2′-f][1,3,2]dioxaphosphepin-4-oxide

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Related products of tetrahydrofuran

(11bR)-2,6-Di-1-pyrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

(11bR)-2,6-Di-1-pyrenyl-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

R-4-oxide-2,6-di-9-anthracenyl-8,9,10,11,12,13,14,15-octahydro-4-hydroxy--Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

R-4-oxide-2,6-di-9-anthracenyl-8,9,10,11,12,13,14,15-octahydro-4-hydroxy--Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin

R-3,3'-bis[4-(trifluoroMethyl)phenyl]-[1,1'-Binaphthalene]-2,2'-diol

R-3,3'-bis[4-(trifluoroMethyl)phenyl]-[1,1'-Binaphthalene]-2,2'-diol

R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

R-3,3'-Bis(phenyl)-1,1'-binaphthyl-2,2'-diyl hydrogenphosphate

(R)-NOBIN

R-3,3'-diiodo-2,2'-bis(MethoxyMethoxy)1,1'-Binaphthalene

R-3,3'-diiodo-2,2'-bis(MethoxyMethoxy)1,1'-Binaphthalene

R-2,2'-bis(methoxymethoxy)-3,3'-diphenyl-1,1'-Binaphthalene

R-2,2'-bis(methoxymethoxy)-3,3'-diphenyl-1,1'-Binaphthalene

R-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol

R-3,3'-Bis(phenyl)-1,1'-bi-2-naphthol

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