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HomeProduct name list1-(TRIISOPROPYLSILYL)PYRROLE

1-(TRIISOPROPYLSILYL)PYRROLE

1-(TRIISOPROPYLSILYL)PYRROLE Structural

What is 1-(TRIISOPROPYLSILYL)PYRROLE?

The Uses of 1-(TRIISOPROPYLSILYL)PYRROLE

1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).

The Uses of 1-(TRIISOPROPYLSILYL)PYRROLE

1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of:

  • ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate
  • heterocyclic base, 3-nitropyrrole
  • 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole

What are the applications of Application

1-(Triisopropylsilyl)pyrrole is a reagent used in perfluoroalkylation and vilsmeter formylation reactions

General Description

1-(Triisopropylsilyl)pyrrole (TISP), a heterocyclic building block, is a pyrrole derivative. TISP has been reported to generate pyrrolic cation radicals during cyclovoltammetric studies, via electroreduction. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).

Properties of 1-(TRIISOPROPYLSILYL)PYRROLE

Boiling point: 78 °C0.4 mm Hg(lit.)
Density  0.904 g/mL at 25 °C(lit.)
refractive index  n20/D 1.492(lit.)
Flash point: 224 °F
storage temp.  Inert atmosphere,2-8°C
form  clear liquid
pka -2.55±0.70(Predicted)
Specific Gravity 0.904
color  Colorless to Almost colorless
Water Solubility  Not miscible in water.
Sensitive  Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN  3540663
CAS DataBase Reference 87630-35-1(CAS DataBase Reference)

Safety information for 1-(TRIISOPROPYLSILYL)PYRROLE

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H319:Serious eye damage/eye irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1-(TRIISOPROPYLSILYL)PYRROLE

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