1-(TRIISOPROPYLSILYL)PYRROLE
- CAS NO.:87630-35-1
- Empirical Formula: C13H25NSi
- Molecular Weight: 223.43
- MDL number: MFCD00054932
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-04-23 13:52:06
What is 1-(TRIISOPROPYLSILYL)PYRROLE?
The Uses of 1-(TRIISOPROPYLSILYL)PYRROLE
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate; heterocyclic base, 3-nitropyrrole and 3-nitropyrrole, required for the synthesis of 1 -(2?-deoxy-β-D-ribofuranosyl)-3-nitropyrrole. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
The Uses of 1-(TRIISOPROPYLSILYL)PYRROLE
1-(Triisopropylsilyl)pyrrole may be employed as reagent in perfluoroalkylation and Vilsmeier formylation reactions. It may be used in the preparation of:
- ethyl 2-(2,4-dinitrophenylhydrazono]-3-[ 1-(triisopropylsily1)-pyrrol-2-yflpropanoate
- heterocyclic base, 3-nitropyrrole
- 3-nitropyrrole, required for the synthesis of 1 -(2′-deoxy-β-D-ribofuranosyl)-3-nitropyrrole
What are the applications of Application
1-(Triisopropylsilyl)pyrrole is a reagent used in perfluoroalkylation and vilsmeter formylation reactions
General Description
1-(Triisopropylsilyl)pyrrole (TISP), a heterocyclic building block, is a pyrrole derivative. TISP has been reported to generate pyrrolic cation radicals during cyclovoltammetric studies, via electroreduction. It participates in various electrophilic substitution reactions specifically at β-position, via reaction with various electrophilic reagents (Br+, I+,NO2+,etc).
Properties of 1-(TRIISOPROPYLSILYL)PYRROLE
Boiling point: | 78 °C0.4 mm Hg(lit.) |
Density | 0.904 g/mL at 25 °C(lit.) |
refractive index | n |
Flash point: | 224 °F |
storage temp. | Inert atmosphere,2-8°C |
form | clear liquid |
pka | -2.55±0.70(Predicted) |
Specific Gravity | 0.904 |
color | Colorless to Almost colorless |
Water Solubility | Not miscible in water. |
Sensitive | Moisture Sensitive |
Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
BRN | 3540663 |
CAS DataBase Reference | 87630-35-1(CAS DataBase Reference) |
Safety information for 1-(TRIISOPROPYLSILYL)PYRROLE
Signal word | Warning |
Pictogram(s) |
Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H319:Serious eye damage/eye irritation |
Precautionary Statement Codes |
P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing. |
Computed Descriptors for 1-(TRIISOPROPYLSILYL)PYRROLE
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