1-Naphthylboronic acid
Synonym(s):1-Naphthaleneboronic acid;1-Naphthylboronic acid;1-naphthalenyl-boronic acid;α-Naphthaleneboronic acid;α-Naphthylboronic acid
- CAS NO.：13922-41-3
- Empirical Formula: C10H9BO2
- Molecular Weight: 171.99
- MDL number: MFCD00019722
- EINECS: 604-119-4
- SAFETY DATA SHEET (SDS)
- Update Date: 2024-04-22 09:54:45
What is 1-Naphthylboronic acid?
Chemical properties
Off-white to pink beige powder. soluble in methanol. Insoluble in water.
The Uses of 1-Naphthylboronic acid
Naphthalene-1-boronic acid can be used:
Methyl 5-bromo-2-(naphthalene-1-yl)benzoate, which is a starting material for the preparation of 9-anthracene-spirobenzofluorene host materials.
A bifunctional polymer used for the hydrolysis of cellulose.
9-(Naphthalene-1-yl)anthracene, which is a key intermediate for the preparation of anthracene derived molecular glass having blue emission.
1-Naphthaleneboronic acid can also be as a substrate in fluorometric boronic acid based saccharide sensors based on the Suzuki homocoupling reactions.
The Uses of 1-Naphthylboronic acid
1-Naphthaleneboronic acid is a useful synthetic intermediate. It is a reagent used to synthesize potassium aryltrifluoroborates which is a convenient precursor of arylboron difluoride lewis acids. It is also useful in the synthesis of polyaromatic hydrocarbons utilizing the Suzuki reaction.
What are the applications of Application
Naphthalene-1-boronic acid is a naphthalene boronic acid building block
Precautions
Incompatible with oxidizing agents. Store in a cool, dry condition in a well sealed container. Store at room temperature.
Properties of 1-Naphthylboronic acid
| Melting point: | 208-214 °C(lit.) |
| Boiling point: | 381.9±25.0 °C(Predicted) |
| Density | 1.21±0.1 g/cm3(Predicted) |
| refractive index | n20D 1.64 (Predicted) |
| storage temp. | Keep in dark place,Sealed in dry,Room Temperature |
| solubility | soluble in DMSO, Methanol |
| pka | 8.53±0.30(Predicted) |
| form | Powder |
| color | Off-white to pink beige |
| Water Solubility | 2.5 g/100 mL |
| BRN | 2937504 |
| InChI | InChI=1S/C10H9BO2/c12-11(13)10-6-5-8-3-1-2-4-9(8)7-10/h1-7,12-13H |
| CAS DataBase Reference | 13922-41-3(CAS DataBase Reference) |
Safety information for 1-Naphthylboronic acid
| Signal word | Warning |
| Pictogram(s) |
 Exclamation Mark Irritant GHS07 |
| GHS Hazard Statements |
H302:Acute toxicity,oral |
| Precautionary Statement Codes |
P264:Wash hands thoroughly after handling. P264:Wash skin thouroughly after handling. P270:Do not eat, drink or smoke when using this product. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P501:Dispose of contents/container to..… |
Computed Descriptors for 1-Naphthylboronic acid
| InChIKey | HUMMCEUVDBVXTQ-UHFFFAOYSA-N |
| SMILES | C1=C2C(C=CC=C2)=CC=C1B(O)O |
1-Naphthylboronic acid manufacturer
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