1-METHOXY-1,3-CYCLOHEXADIENE
Synonym(s):2,3-Dihydroanisole
- CAS NO.:2161-90-2
- Empirical Formula: C7H10O
- Molecular Weight: 110.15
- MDL number: MFCD00001533
- EINECS: 218-483-3
- SAFETY DATA SHEET (SDS)
- Update Date: 2023-05-25 18:01:00
What is 1-METHOXY-1,3-CYCLOHEXADIENE?
The Uses of 1-METHOXY-1,3-CYCLOHEXADIENE
1-Methoxy-1,3-cyclohexadiene was used in the following studies:
- Synthesis of tetracyclic polyhydroxyquinones via Diels-Alder reaction.
- Synthesis of tetra-ortho-substituted biaryls via Diels-Alder reaction.
- Synthesis of optically active form of dihydroisocoumarin fragment of the gastroprotective natural product AI-77-B, via regiospecific Diels-Alder reaction with an acetylenic ester derivative.
Synthesis Reference(s)
Tetrahedron Letters, 13, p. 4195, 1972 DOI: 10.1016/S0040-4039(01)94273-X
General Description
1-Methoxy-1,3-cyclohexadiene is a useful Diels-Alder diene employed in Diels-Alder cycloadditions. It undergoes Diels-Alder reaction with alkyne to yield anisole derivative.
Properties of 1-METHOXY-1,3-CYCLOHEXADIENE
Melting point: | 96-97 °C |
Boiling point: | 40 °C/15 mmHg (lit.) |
Density | 0.929 g/mL at 25 °C (lit.) |
refractive index | n |
Flash point: | 80 °F |
Safety information for 1-METHOXY-1,3-CYCLOHEXADIENE
Signal word | Warning |
Pictogram(s) |
Flame Flammables GHS02 Exclamation Mark Irritant GHS07 |
GHS Hazard Statements |
H226:Flammable liquids |
Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P280:Wear protective gloves/protective clothing/eye protection/face protection. P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. |
Computed Descriptors for 1-METHOXY-1,3-CYCLOHEXADIENE
New Products
Tert-butyl bis(2-chloroethyl)carbamate 4-Methylphenylacetic acid N-Boc-D-alaninol N-BOC-D/L-ALANINOL 3-Morpholino-1-(4-nitrophenyl)-5,6-dihydropyridin- 2(1H)-one Furan-2,5-Dicarboxylic Acid Tropic acid 1,1’-CARBONYLDIIMIDAZOLE DIETHYL AMINOMALONATE HYDROCHLORIDE R-2-BENZYLOXY PROPIONIC ACID 1,1’-CARBONYLDI (1,2-4 TRIAZOLE) N-METHYL INDAZOLE-3-CARBOXYLIC ACID (2-Hydroxyphenyl)acetonitrile 4-Bromopyrazole 5-BROMO-2CYANO PYRIDINE 5,6-Dimethoxyindanone 5-broMo-2-chloro-N-cyclopentylpyriMidin-4-aMine 2-(Cyanocyclohexyl)acetic acid 4-methoxy-3,5-dinitropyridine 2-aminopropyl benzoate hydrochloride 1-(4-(aminomethyl)benzyl)urea hydrochloride diethyl 2-(2-((tertbutoxycarbonyl)amino) ethyl)malonate tert-butyl 4- (ureidomethyl)benzylcarbamate Ethyl-2-chloro((4-methoxyphenyl)hydrazono)acetateRelated products of tetrahydrofuran
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