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HomeProduct name list1-Amino-7-naphthol

1-Amino-7-naphthol

  • CAS NO.:118-46-7
  • Empirical Formula: C10H9NO
  • Molecular Weight: 159.18
  • MDL number: MFCD00004031
  • EINECS: 204-252-4
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-11-06 14:42:05
1-Amino-7-naphthol Structural

What is 1-Amino-7-naphthol?

Chemical properties

grey to grey-brown granular powder

The Uses of 1-Amino-7-naphthol

Sulfonation gives 1-amino-7-hydroxynaphthalene-4-sulfonic acid. The N-acetyl derivative is an important coupling component for after-chrome and metal-complex dyes, e.g., C.I. Mordant Black 38 and C.I. Acid Black 60.

What are the applications of Application

8-Amino-2-naphthol is a chiral organocatalyst

Production Methods

The sodium salt of 1-aminonaphthalene-7-sulfonic acid is added to 80 % potassium hydroxide at 210℃, and the reaction is completed by heating for 6 h at 230℃. After dilution and careful acidification with hydrochloric acid, the acid solution is screened to remove impurities and neutralized to precipitate 159 in 80 % yield (mp 207℃).

Properties of 1-Amino-7-naphthol

Melting point: 206-210 °C(lit.)
Boiling point: 284.68°C (rough estimate)
Density  1.1202 (rough estimate)
refractive index  1.6070 (estimate)
solubility  soluble in Methanol
form  Powder or Crystals
pka pK1: 4.20(+1) (25°C)
color  Gray to brown
Water Solubility  slightly soluble
Sensitive  Light Sensitive
CAS DataBase Reference 118-46-7(CAS DataBase Reference)
EPA Substance Registry System 2-Naphthalenol, 8-amino- (118-46-7)

Safety information for 1-Amino-7-naphthol

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P304+P340:IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405:Store locked up.

Computed Descriptors for 1-Amino-7-naphthol

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