1-ACETYL-1-CYCLOPENTENE
- CAS NO.：16112-10-0
- Empirical Formula: C7H10O
- Molecular Weight: 110.15
- MDL number: MFCD00799464
- SAFETY DATA SHEET (SDS)
- Update Date: 2022-12-30 16:20:48
What is 1-ACETYL-1-CYCLOPENTENE?
The Uses of 1-ACETYL-1-CYCLOPENTENE
1-Acetyl-1-cyclopentene may be used in the preparation of the following allenylcycloalkanes:
- 1-vinylidenyl-2-[4-(trimethylsilyl)-3-butynyl]-cyclopentane
- 1-vinylidenyl-2-(3-butynyl)-cyclopentane
What are the applications of Application
1-Acetyl-1-cyclopentene is a ketone-containing compound used for proteomics research
Synthesis Reference(s)
The Journal of Organic Chemistry, 44, p. 450, 1979 DOI: 10.1021/jo01317a033
Tetrahedron Letters, 15, p. 1623, 1974
General Description
1-Acetyl-1-cyclopentene is a cyclic alkene. Its lithium enolate undergoes Brook rearrangement-mediated [3+4] annulation with 3-alkyl-3-haloacryloylsilanes to afford tricyclo[5.3.0.01,4]decenone derivatives. Asymmetric oxidative Heck reaction of 1-acetyl-1-cyclopentene in the presence of a Pd-ligand has been reported.
Properties of 1-ACETYL-1-CYCLOPENTENE
| Boiling point: | 70 °C/20 mmHg (lit.) |
| Density | 0.955 g/mL at 25 °C (lit.) |
| refractive index | n20/D 1.483(lit.) |
| Flash point: | 59 °C |
Safety information for 1-ACETYL-1-CYCLOPENTENE
| Signal word | Warning |
| Pictogram(s) |
 Flame Flammables GHS02 |
| GHS Hazard Statements |
H225:Flammable liquids |
| Precautionary Statement Codes |
P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking. P233:Keep container tightly closed. P240:Ground/bond container and receiving equipment. P241:Use explosion-proof electrical/ventilating/lighting/…/equipment. P242:Use only non-sparking tools. P243:Take precautionary measures against static discharge. P280:Wear protective gloves/protective clothing/eye protection/face protection. P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower. P370+P378:In case of fire: Use … for extinction. P403+P235:Store in a well-ventilated place. Keep cool. P501:Dispose of contents/container to..… |
Computed Descriptors for 1-ACETYL-1-CYCLOPENTENE
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