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HomeProduct name list1-ACENAPHTHENOL

1-ACENAPHTHENOL

Synonym(s):1-Hydroxyacenaphthene

  • CAS NO.:6306-07-6
  • Empirical Formula: C12H10O
  • Molecular Weight: 170.21
  • MDL number: MFCD00003808
  • EINECS: 228-618-8
  • SAFETY DATA SHEET (SDS)
  • Update Date: 2023-06-08 17:06:34
1-ACENAPHTHENOL Structural

What is 1-ACENAPHTHENOL?

Description

1-Acenaphthenol is a white to cream solid in appearance. It is almost insoluble in water. 1-Acenaphthenol is a stable and combustible chemical substance. It is incompatible with strong oxidising agents. It is used in the syntheses of organic compounds. Exposures to 1-acenaphthenol cause irritant effects. It is harmful by ingestion, inhalation, as well as through skin absorption. There are no complete data on the toxicology of 1-acenaphthenol.

Chemical properties

1-Acenaphthenol is a white to cream solid in appearance. It is almost insoluble in water. 1-Acenaphthenol is a stable and combustible chemical substance. It is incompatible with strong oxidizing agents. It is used in the syntheses of organic compounds.

The Uses of 1-ACENAPHTHENOL

1-Acenaphthenol is a product of the microbial metabolism and photolysis of acenaphthene, of acenaphthene, a polycyclic hydrocarbon that has potential to act as polyploidizing agents in plants. 1-Acenaphthenol is also a known substrate of dihydrodiol dehydrogenases.

Health Hazard

Exposures to 1-acenaphthenol cause irritant effects. It is harmful by ingestion, inhalation, or skin absorption. There are no complete data on the toxicology of 1-acenaphthenol.

Purification Methods

If highly coloured (yellow), dissolve it in boiling *benzene (14g in 200mL), add charcoal (0.5g), filter it through a heated funnel, concentrate to 100mL and cool to give almost colourless needles. *Benzene vapour is TOXIC; use an efficient fume cupboard. The acetate has b 166-168o/5mm (bath temperature 180-185o). [Cason Org Synth Coll Vol III 3 1955.] It can also be recrystallised from *C6H6 or EtOH [Fieser & Cason J Am Chem Soc 62 432 1940]. It forms a brick-red crystalline complex with 2,4,5,7-tetranitrofluoren-9-one which is recrystallised from AcOH and is dried in a vacuum over KOH and P2O5 at room temperature, m 170-172o [Newman & Lutz J Am Chem Soc 78 2469 1956]. [Beilstein 6 IV 4623.]

Properties of 1-ACENAPHTHENOL

Melting point: 145-148 °C (lit.)
Boiling point: 369℃
Density  1.290
Flash point: 129℃
storage temp.  -20°C Freezer
solubility  Chloroform (Slightly, Sonicated), Methanol (Slightly)
form  Solid
pka 13.68±0.20(Predicted)
color  Yellow to Dark Yellow
BRN  2048222
Stability: Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference 6306-07-6(CAS DataBase Reference)

Safety information for 1-ACENAPHTHENOL

Signal word Warning
Pictogram(s)
ghs
Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H315:Skin corrosion/irritation
H319:Serious eye damage/eye irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

Computed Descriptors for 1-ACENAPHTHENOL

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