(+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one

CAS NO.：13173-09-6
Empirical Formula: C7H8O
Molecular Weight: 108.14
MDL number: MFCD00066201
SAFETY DATA SHEET (SDS)
Update Date: 2022-08-23 14:33:43

What is (+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one?

The Uses of (+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one

Bicyclo[3.2.0]hept-2-en-6-one is widely utilized to study enantioselective Baeyer-Villiger oxidation of (±)-cis-bicyclo(3.2.0)hept-2-en-6-one. It is used in the synthesis of a series of chalcone derivatives by reacting with arylaldehydes. It is also used to analyze the extremophile enzymes (monooxygenase and hydrolases) in microorganisms which are isolated from a deep-water petroleum reservoir and at high temperatures using fluorogenic assays and multibioreactions.

General Description

(±)-cis-bicyclo(3.2.0)hept-2-en-6-one undergoes preparative scale Baeyer–Villiger biooxidation at high concentration using recombinant Escherichia coli biocatalyst and adsorbent resin (in situ substrate feeding and product removal).

Properties of (+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one

Boiling point:	158-160 °C(lit.)
Density	1.025 g/mL at 25 °C(lit.)
refractive index	n20/D 1.4820(lit.)
storage temp.	under inert gas (nitrogen or Argon) at 2-8°C
Sensitive	Air Sensitive

Safety information for (+/-)-cis-Bicyclo[3.2.0]hept-2-en-6-one

Signal word	Danger
Pictogram(s)	Corrosion Corrosives GHS05 Exclamation Mark Irritant GHS07
GHS Hazard Statements	H302:Acute toxicity,oral H315:Skin corrosion/irritation H318:Serious eye damage/eye irritation H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes	P261:Avoid breathing dust/fume/gas/mist/vapours/spray. P280:Wear protective gloves/protective clothing/eye protection/face protection. P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.