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97-93-8

97-93-8 structural image
Product Name: Triethylaluminum
Formula: C6H15Al
Synonyms: Aluminumtriethanide
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Aluminum triethyl appears as a colorless liquid. Flammable gas is produced on contact with water. (USCG, 1999)
Color/Form Colorless liquid
Boiling Point 367.9 °F at 760 mmHg (USCG, 1999)
Melting Point -51 °F (USCG, 1999)
Flash Point -63 °F (NFPA, 2010)
Solubility Miscible with saturated hydrocarbons
Density 0.836 at 68 °F (USCG, 1999) - Less dense than water; will float
Vapor Pressure 0.02 [mmHg]
Stability/Shelf Life Low melting solids or colorless, volatile liquids. /Alkylaluminum halides/
Decomposition DECOMP TO AL(OH)3 + C2H6
Viscosity 2.6 mPa.s (millipascal second) at 25 °C
Heat of Combustion -18364 BTU/lb= -10202 cal/g = -426.85 E5 J/kg.
Heat of Vaporization 216 BTU/lb= 120 cal/g = 5.02 E5 J/kg.
Refractive Index INDEX OF REFRACTION: 1.480 @ 6.5 °C/D
Other Experimental Properties In the temperature range 60-120 °C the monomer (Al(C2H5)3) was the dominant form of aluminum triethyl vapor.
Chemical Classes Metals -> Metals, Organic Compounds

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Flame
Flammables
GHS02

Corrosion
Corrosives
GHS05

Exclamation Mark
Irritant
GHS07

Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H250:Pyrophoric liquids; Pyrorophoric solids
H252:Self-heating substances and mixtures
H260:Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases
H304:Aspiration hazard
H314:Skin corrosion/irritation
H336:Specific target organ toxicity,single exposure; Narcotic effects
H373:Specific target organ toxicity, repeated exposure
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P231+P232:Handle under inert gas. Protect from moisture.
P301+P330+P331:IF SWALLOWED: Rinse mouth. Do NOT induce vomiting.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378:In case of fire: Use … for extinction.

COMPUTED DESCRIPTORS

Molecular Weight 114.16 g/mol
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 0
Rotatable Bond Count 3
Exact Mass 114.0989139 g/mol
Monoisotopic Mass 114.0989139 g/mol
Topological Polar Surface Area 0 Ų
Heavy Atom Count 7
Formal Charge 0
Complexity 25.7
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Aluminum triethyl appears as a colorless liquid. Flammable gas is produced on contact with water. (USCG, 1999)