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95-92-1

95-92-1 structural image
Product Name: Diethyl oxalate
Formula: C6H10O4
Synonyms: Diethyl oxalate;Oxalic acid diethyl ester
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Ethyl oxalate appears as a colorless liquid. Slightly denser than water and insoluble in water. Hence sinks in water. May irritate skin and mucous membranes; may be mildly toxic by ingestion; may emit irritating fumes in a fire. Vapors are much heavier than air. Used as a solvent for plastics and in the manufacture of perfumes and pharmaceuticals.
Color/Form COLORLESS, OILY LIQUID
Odor AROMATIC ODOR
Boiling Point 185.7 °C @ 760 MM HG
Melting Point -38.5 °C
Flash Point 168 °F (NFPA, 2010)
Solubility SPARINGLY SOL IN WATER WHICH DECOMP IT GRADUALLY; MISCIBLE WITH USUAL ORG SOLVENTS
Density 1.0785 @ 20 °C/4 °C
Vapor Density 5.04
Vapor Pressure 0.41 [mmHg]
Stability/Shelf Life UNSTABLE
Refractive Index INDEX OF REFRACTION: 1.4101 @ 20 °C/D; SADTLER REFERENCE NUMBER: 5267 (IR, PRISM); MAX ABSORPTION (ALCOHOL): 225 NM (LOG E= 2.6)
Kovats Retention Index 948 940 948
Other Experimental Properties CAN REACT WITH OXIDIZING MATERIALS
Chemical Classes Other Classes -> Esters, Other

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Corrosion
Corrosives
GHS05

Exclamation Mark
Irritant
GHS07

Health Hazard
GHS08
GHS Hazard Statements H302:Acute toxicity,oral
H314:Skin corrosion/irritation
H373:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P314:Get medical advice/attention if you feel unwell.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 146.14 g/mol
XLogP3 0.6
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 4
Rotatable Bond Count 5
Exact Mass 146.05790880 g/mol
Monoisotopic Mass 146.05790880 g/mol
Topological Polar Surface Area 52.6 Ų
Heavy Atom Count 10
Formal Charge 0
Complexity 114
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Ethyl oxalate appears as a colorless liquid. Slightly denser than water and insoluble in water. Hence sinks in water. May irritate skin and mucous membranes; may be mildly toxic by ingestion; may emit irritating fumes in a fire. Vapors are much heavier than air. Used as a solvent for plastics and in the manufacture of perfumes and pharmaceuticals.

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