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74-85-1

74-85-1 structural image
Product Name: Ethylene
Formula: C2H4
Synonyms: Ethene
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Ethylene appears as a colorless gas with a sweet odor and taste. It is lighter than air. It is easily ignited and a flame can easily flash back to the source of the leak. Under prolonged exposure to fire or heat the containers may rupture violently and rocket. Can cause explosion.
Color/Form Colorless gas
Odor Sweet
Taste Tasteless
Boiling Point -154.7 °F at 760 mmHg (USCG, 1999)
Melting Point -272.4 °F (USCG, 1999)
Flash Point -213 °F (approx.) (USCG, 1999)
Solubility In water, 131 mg/L at 25 °C
Density 0.569 at -154.84 °F (USCG, 1999) - Less dense than water; will float
Vapor Density 0.98 (Air = 1)
Vapor Pressure Vapor pressure 4,040 kPa (-1.5 °C)
LogP log Kow = 1.13
Henry's Law Constant Henry's Law constant = 0.228 atm-cu m/mole at 25 °C
Stability/Shelf Life Stable under recommended storage conditions.
Autoignition Temperature 842 °F (USCG, 1999)
Decomposition Hazardous decomposition products formed under fire conditions: Carbon oxides.
Viscosity 0.01 mPa.s 20 °C
Corrosivity Ethylene is a noncorrosive gas.
Heat of Combustion -1411.2 kJ/mol (gas)
Heat of Vaporization 13.53 kJ/mol at -103.77 °C
Surface Tension 16 dynes/cm = 0.016 N/m at -104 °C
Polymerization Hazardous polymerization may occur.
Odor Threshold Odor Threshold Low: 17.0 [ppm] Odor Threshold High: 959.0 [ppm] [ACGIH] Detection odor threshold from AIHA (mean = 270 ppm)
Refractive Index Index of refraction: 1.363 at -100 °C/D
Kovats Retention Index 178.1 164 166 158 178 166 166 165 165 165 165 165 188
Other Experimental Properties Monoclinic prisms when it solidifies at -181 °C
Chemical Classes Toxic Gases & Vapors -> Simple Asphyxiants

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Flame
Flammables
GHS02

Gas Cylinder
Compressed Gases
GHS04

Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H220:Flammable gases
H280:Gases under pressure
H336:Specific target organ toxicity,single exposure; Narcotic effects
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P271:Use only outdoors or in a well-ventilated area.
P405:Store locked up.
P403+P233:Store in a well-ventilated place. Keep container tightly closed.
P410+P403:Protect from sunlight. Store in a well-ventilated place.

COMPUTED DESCRIPTORS

Molecular Weight 28.05 g/mol
XLogP3 1.2
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 0
Rotatable Bond Count 0
Exact Mass 28.0313001276 g/mol
Monoisotopic Mass 28.0313001276 g/mol
Topological Polar Surface Area 0 Ų
Heavy Atom Count 2
Formal Charge 0
Complexity 0
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Ethylene appears as a colorless gas with a sweet odor and taste. It is lighter than air. It is easily ignited and a flame can easily flash back to the source of the leak. Under prolonged exposure to fire or heat the containers may rupture violently and rocket. Can cause explosion.

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