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57018-04-9

57018-04-9 structural image
Product Name: Tolclofos-methyl
Formula: C9H11Cl2O3PS
Synonyms: O-(2,6-Dichloro-4-methylphenyl) O,O-dimethyl phosphorothioate
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CHEMICAL AND PHYSICAL PROPERTIES

Color/Form White crystals from methanol
Melting Point 79-79.5 °C
Flash Point >100 °C (>212 °F)
Solubility In water, 1.10 mg/L at 15 °C
Vapor Pressure VP: 4.27X10-4 mm Hg at 20 °C
LogP log Kow = 4.56
Stability/Shelf Life Stable under recommended storage conditions.
Collision Cross Section 149.82 Ų [M+H]+
Kovats Retention Index 1861 1882
Other Experimental Properties Colorless to light brown solid (technical toclofos-methyl)

SAFETY INFORMATION

Signal word Warning
Pictogram(s)

Exclamation Mark
Irritant
GHS07

Environment
GHS09
GHS Hazard Statements H317:Sensitisation, Skin
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P261:Avoid breathing dust/fume/gas/mist/vapours/spray.
P272:Contaminated work clothing should not be allowed out of the workplace.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P302+P352:IF ON SKIN: wash with plenty of soap and water.
P333+P313:IF SKIN irritation or rash occurs: Get medical advice/attention.

COMPUTED DESCRIPTORS

Molecular Weight 301.13 g/mol
XLogP3 4.7
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 4
Rotatable Bond Count 4
Exact Mass 299.9543578 g/mol
Monoisotopic Mass 299.9543578 g/mol
Topological Polar Surface Area 59.8 Ų
Heavy Atom Count 16
Formal Charge 0
Complexity 260
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Tolclofos-methyl is an organic thiophosphate that is 2,6-dichloro-4-methylphenol in which the hydrogen of the hydroxy group group has been replaced by a dimethoxyphosphorothioyl group. Tolclofos-methyl is a phospholipid biosynthesis inhibitor and fungicide that is used for controlling soil-borne diseases caused by Typhula incarnata, Corticium rolfsii, Typhula ishikariensis, and Rhizoctonia solani. It has a role as an antifungal agrochemical. It is an organic thiophosphate and a dichlorobenzene.