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358-23-6

358-23-6 structural image
Product Name: Trifluoromethanesulfonic anhydride
Formula: C2F6O5S2
Synonyms: Perfluoromethanesulfonic anhydride solution;Tf2O;Triflic anhydride;Triflic anhydride solution;Trifluoromethanesulfonic anhydride
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Colorless hygroscopic liquid; [Merck Index] Clear colorless liquid; [Sigma-Aldrich MSDS]
Vapor Pressure 8.0 [mmHg]
Chemical Classes Other Classes -> Acid Anhydrides, Other

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Flame Over Circle
Oxidizers
GHS03

Corrosion
Corrosives
GHS05

Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H272:Oxidising liquids;Oxidising solids
H302:Acute toxicity,oral
H314:Skin corrosion/irritation
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220:Keep/Store away from clothing/…/combustible materials.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 282.14 g/mol
XLogP3 1.6
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 11
Rotatable Bond Count 2
Exact Mass 281.90913442 g/mol
Monoisotopic Mass 281.90913442 g/mol
Topological Polar Surface Area 94.3 Ų
Heavy Atom Count 15
Formal Charge 0
Complexity 370
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Trifluoromethanesulfonic anhydride finds various applications across different fields of chemistry due to its strong electrophilic nature and its ability to activate functional groups. Trifluoromethanesulfonic anhydride is widely used in organic synthesis as a versatile reagent for various transformations.

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