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26628-22-8

26628-22-8 structural image
Product Name: Sodium azide
Formula: N3Na
Synonyms: Additive Screening Solution 45/Kit-No 78374;Hydrazoic acid sodium salt;NSC 3072;Sodium azide solution
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Sodium azide appears as a colorless crystalline solid. Density 1.85 g / cm3. Burns in air and may explode if large quantities are involved. Toxic by ingestion. Toxic oxides of nitrogen are produced in fires.
Color/Form Colorless hexagonal crystals
Odor Odorless (with traces of water fishy smelling because of HN3 formation)
Boiling Point Decomposes in vacuum (EPA, 1998)
Melting Point Decomposes at 527 °F to sodium and nitrogen (EPA, 1998)
Flash Point Not flammable (EPA, 1998)
Solubility 50 to 100 mg/mL at 72 °F (NTP, 1992)
Density 1.846 at 68 °F (EPA, 1998) - Denser than water; will sink
Vapor Pressure 1 Pa at 20 °C
Stability/Shelf Life Stable under recommended storage conditions.
Decomposition Hazardous decomposition products formed under fire conditions - Sodium oxides.
Corrosivity Very corrosive to aluminum, moderate to copper and lead
Ionization Potential 11.70 eV
Dissociation Constants pKb = 9.3
Other Experimental Properties Decomposes at 275 °C to sodium and nitrogen. Decomposes in vacuum.
Chemical Classes Other Uses -> Explosives

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Skull and Crossbones
Acute Toxicity
GHS06

Health Hazard
GHS08

Environment
GHS09
GHS Hazard Statements H373:Specific target organ toxicity, repeated exposure
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P262:Do not get in eyes, on skin, or on clothing.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P314:Get medical advice/attention if you feel unwell.

COMPUTED DESCRIPTORS

Molecular Weight 65.010 g/mol
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 2
Rotatable Bond Count 0
Exact Mass 64.99899129 g/mol
Monoisotopic Mass 64.99899129 g/mol
Topological Polar Surface Area 3 Ų
Heavy Atom Count 4
Formal Charge 0
Complexity 15.5
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 2
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Sodium azide appears as a colorless crystalline solid. Density 1.85 g / cm3. Burns in air and may explode if large quantities are involved. Toxic by ingestion. Toxic oxides of nitrogen are produced in fires.