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111-15-9

111-15-9 structural image
Product Name: Ethylene glycol monoethyl ether acetate
Formula: C6H12O3
Synonyms: 1-Acetoxy-2-ethoxyethane;2-Ethoxyethyl acetate;Cellosolve acetate;Ethylene glycol monoethyl ether acetate;Ethylene glycol monoethyl ether acetate, Ethyl glycol acetate, Acetic acid 2-ethoxyethyl ester
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Ethylene glycol monoethyl ether acetate appears as a clear colorless liquid with a pleasant odor. Flash point of 120 °F. Less dense than water. Vapors are heavier than air.
Color/Form Colorless liquid
Odor MILD ESTER-LIKE ODOR BECOMES OBJECTIONABLE IN HIGH CONCN ...
Taste ... A BITTER ACID TASTE
Boiling Point 313 °F at 760 mmHg (NTP, 1992)
Melting Point -79.1 °F (NTP, 1992)
Flash Point 135 °F (NTP, 1992)
Solubility greater than or equal to 100 mg/mL at 66 °F (NTP, 1992)
Density 0.974 at 68 °F (USCG, 1999) - Less dense than water; will float
Vapor Density 4.72 (NTP, 1992) - Heavier than air; will sink (Relative to Air)
Vapor Pressure 1.2 mmHg at 68 °F ; 3.8 mmHg at 86 °F (NTP, 1992)
LogP log Kow = 0.24
Henry's Law Constant Henry's Law constant = 3.20X10-6 atm-cu m/mole at 25 °C
Autoignition Temperature 715 °F (USCG, 1999)
Decomposition WHEN HEATED TO DECOMPOSITION IT EMITS ACRID SMOKE AND IRRITATING FUMES.
Viscosity 1.32 cP at 20 °C
Heat of Vaporization 130 Btu/lb= 74 cal/g= 3.1X10X5 J/kg
Surface Tension 31.8 dynes/cm at 25 °C
Odor Threshold Odor Threshold Low: 0.06 [mmHg] Odor Threshold High: 0.13 [mmHg] Detection odor threshold from AIHA (mean = 0.06 ppm)
Refractive Index Index of refraction: 1.4054 at 20 °C
Relative Evaporation Rate 0.20 (n-butyl acetate = 1)
Kovats Retention Index 880.8 888 882 875 877.7 859 876 876 874 876 872
Other Experimental Properties CONVERSION FACTORS: 1 PPM= 5.4 MG/CU M; 1 MG/L= 185 PPM
Chemical Classes Solvents -> Glycol Ethers (E Series)

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Flame
Flammables
GHS02

Exclamation Mark
Irritant
GHS07

Health Hazard
GHS08
GHS Hazard Statements H226:Flammable liquids
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P308+P313:IF exposed or concerned: Get medical advice/attention.

COMPUTED DESCRIPTORS

Molecular Weight 132.16 g/mol
XLogP3 0.3
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 3
Rotatable Bond Count 5
Exact Mass 132.078644241 g/mol
Monoisotopic Mass 132.078644241 g/mol
Topological Polar Surface Area 35.5 Ų
Heavy Atom Count 9
Formal Charge 0
Complexity 80.4
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Ethylene glycol monoethyl ether acetate appears as a clear colorless liquid with a pleasant odor. Flash point of 120 °F. Less dense than water. Vapors are heavier than air.

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