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110-05-4

110-05-4 structural image
Product Name: Di-tert-butyl peroxide
Formula: C8H18O2
Synonyms: tert-Butyl peroxide;Di-tert-butyl peroxide;Di-tert-butyl peroxide;tert-Butyl peroxide
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Di-tert-butyl peroxide is a clear colorless liquid. (NTP, 1992)
Color/Form Clear, water-white liquid
Boiling Point 232 °F at 760 mmHg (NTP, 1992)
Melting Point -40 °F (NTP, 1992)
Flash Point 65 °F (NTP, 1992)
Solubility less than 1 mg/mL at 70 °F (NTP, 1992)
Density 0.704 at 68 °F (NTP, 1992) - Less dense than water; will float
Vapor Density 5.03 (NTP, 1992) - Heavier than air; will sink (Relative to Air)
Vapor Pressure 19.51 mmHg at 68 °F (NTP, 1992)
LogP log Kow = 3.2 at 22 °C, pH 7.2
Stability/Shelf Life Stable under recommended storage conditions.
Decomposition When heated to decomposition it emits acrid smoke and fumes.
Refractive Index Index of refraction: 1.3890 @ 20 °C/D
Other Experimental Properties Evaporates with decomposition and without violence at 91 °C
Chemical Classes Other Classes -> Peroxides, Organic

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Flame
Flammables
GHS02

Health Hazard
GHS08
GHS Hazard Statements H225:Flammable liquids
H242:Self-reactive substances and mixtures; and Organic peroxides
H341:Germ cell mutagenicity
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P220:Keep/Store away from clothing/…/combustible materials.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P410:Protect from sunlight.
P411+P235:Store at temperatures not exceeding … oC/…oF. Keep cool.

COMPUTED DESCRIPTORS

Molecular Weight 146.23 g/mol
XLogP3 2.1
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 2
Rotatable Bond Count 3
Exact Mass 146.130679813 g/mol
Monoisotopic Mass 146.130679813 g/mol
Topological Polar Surface Area 18.5 Ų
Heavy Atom Count 10
Formal Charge 0
Complexity 80.8
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Di-tert-butyl peroxide is a clear colorless liquid. (NTP, 1992)

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