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109-86-4

109-86-4 structural image
Product Name: 2-Methoxyethanol
Formula: C3H8O2
Synonyms: Water;1-Pentanol;2-Methoxyethanol;Ethylene glycol monomethyl ether;Methyl glycol
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Ethylene glycol monomethyl ether appears as a clear colorless liquid. Flash point of 110 °F. Less dense than water. Vapors are heavier than air.
Color/Form Colorless liquid
Odor Mild agreeable odor
Taste Bitter
Boiling Point 257 °F at 768 mmHg (NTP, 1992)
Melting Point -121.2 °F (NTP, 1992)
Flash Point 107 °F (NTP, 1992)
Solubility greater than or equal to 100 mg/mL at 70 °F (NTP, 1992)
Density 0.966 at 68 °F (USCG, 1999) - Less dense than water; will float
Vapor Density 2.62 (NTP, 1992) - Heavier than air; will sink (Relative to Air)
Vapor Pressure 6.2 mmHg at 68 °F ; 10 mmHg at 71.6 °F (NTP, 1992)
LogP -0.77
Henry's Law Constant Henry's Law constant = 3.3X10-7 atm-cu m/mol at 25 °C
Stability/Shelf Life Heat /contributes to instability/
Autoignition Temperature 551 °F (USCG, 1999)
Decomposition Thermal decomposition 204 - 232 °C
Corrosivity Methyl cellosolve will attack some forms of plastics, rubber, and coatings.
Heat of Combustion -5250 cal/g
Heat of Vaporization 45.17 kJ/mol at 25 °C; 37.54 kJ/mol at 124.1 °C
Surface Tension 30.84 mN/m at 25 °C
Ionization Potential 9.60 eV
Odor Threshold Odor Threshold Low: 0.09 [mmHg] Odor Threshold High: 61.0 [mmHg] Detection odor threshold from AIHA (mean = 2.4 ppm)
Refractive Index Index of refraction: 1.4024 at 20 °C/D
Dissociation Constants 14.8 (at 25 °C)
Relative Evaporation Rate 0.5 (n-Butyl acetate = 1)
Kovats Retention Index 629 629 617 630 626 623 612.3 611.8 618 616 617 616 617 616
Other Experimental Properties Ratio of Specific Heats of vapor (gas): 1.079; Latent Heat of Vaporization: 223 BTU/lb = 124 cal/g = 5.19X10+3 J/kg
Chemical Classes Solvents -> Glycol Ethers (E Series)

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Flame
Flammables
GHS02

Exclamation Mark
Irritant
GHS07

Health Hazard
GHS08
GHS Hazard Statements H226:Flammable liquids
H370:Specific target organ toxicity, single exposure
H373:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.

COMPUTED DESCRIPTORS

Molecular Weight 76.09 g/mol
XLogP3 -0.8
Hydrogen Bond Donor Count 1
Hydrogen Bond Acceptor Count 2
Rotatable Bond Count 2
Exact Mass 76.052429494 g/mol
Monoisotopic Mass 76.052429494 g/mol
Topological Polar Surface Area 29.5 Ų
Heavy Atom Count 5
Formal Charge 0
Complexity 14.4
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Ethylene glycol monomethyl ether appears as a clear colorless liquid. Flash point of 110 °F. Less dense than water. Vapors are heavier than air.

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