Thiophosgene
| Price | USD1.00 | USD2.00 |
| Packge | 1KG | 1KG |
- Min. Order:1KG
- Supply Ability:200kg
- Time:2019-09-02
Product Details
- Product NameThiophosgene
- CAS No.463-71-8
- EINECS No.207-341-6
- MFCCl2S
- MW114.98
- AppearanceLiquidA reddish liquid
- storage temp. 2-8°C
- density 1.508
- Water Solubility slow decomposition in cold, fast in hot water
- Boiling point 73 °C
- Melting point <25 °C
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Product Name:
Synonyms:
thio-carbonicdichlorid;thiocarbonicdichloride;Thiocarbonyl dichloride;thio-carbonylchlorid;thiocarbonyldichloride;Thiofosgen;Carbon chlorosulfide;carbonchlorosulfide
CAS:
MF:
CCl2S
MW:
114.98
EINECS:
207-341-6
Mol File:
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Thiophosgene Chemical Properties
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Boiling point
73 °C
density
1.508
vapor density
4 (vs air)
refractive index
n20/D 1.548(lit.)
Fp
62 °C
storage temp.
2-8°C
form
Solid
color
White to yellow
Water Solubility
slow decomposition in cold, fast in hot water
BRN
1633495
Stability:
Stable. but reacts violently with water to produce toxic fumes. Incompatible with water, alcohols. Refrigerate at 2-8 C.
CAS DataBase Reference
NIST Chemistry Reference
EPA Substance Registry System
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Safety Information
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Hazard Codes
Risk Statements
Safety Statements
RIDADR
UN 2474 6.1/PG 2
WGK Germany
1
RTECS
XN2450000
F
HazardClass
6.1(a)
PackingGroup
II
HS Code
28530090
Hazardous Substances Data
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Thiophosgene Usage And Synthesis
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Chemical Properties
Reddish liquid. Decomposes in water and alcohol; soluble in ether.
Chemical Properties
A clear dark red to reddish-yellow liquid. Sharp, choking odor.
Uses
Thiophosgene is a photo degradation product of the agricultural fungicide Folpet (F402000).
General Description
A reddish liquid. Boiling point 73.5°C. A severe eye irritant. May severely burn skin on contact. Very toxic by inhalation and by skin absorption.
Air & Water Reactions
Reacts with water to evolve hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot.
Reactivity Profile
Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids.
Hazard
Toxic by ingestion and inhalation.
Health Hazard
Inhalation causes irritation of respiratory system and delayed pulmonary edema. Vapor irritates eyes. Liquid burns skin and eyes. Ingestion causes irritation of mouth and stomach.
Safety Profile
Poison by intravenous route. Moderately toxic by ingestion. A skin, mucous membrane, and severe eye irritant. When heated to decomposition it emits very toxic fumes of Cland SOx. See also PHOSGENE.
Potential Exposure
Primary irritant (w/o allergic reaction). There is not large-scale production of the chemical in the United States It is used to make other chemicals and in laboratory synthesis.
Shipping
UN2474 Thiophosgene, Hazard class: 6.1; Labels: 6.1-Poison Inhalation Hazard; Inhalation Hazard Zone B. PG 2. STN: 49 232 98.
Incompatibilities
Vapors may form explosive mixture with air. Incompatible with water and alcohols. Reacts with water releasing toxic hydrogen chloride, carbon disulfide, and carbon dioxide. Reaction is slow unless the water is hot. Decomposes above 200℃ to highly flammable carbon bisulfide and carbon tetrachloride. Corrodes metals, rubber and some plastics in the presence of moisture. Thiophosgene is incompatible with acids, diazo and azo compounds, halocarbons, isocyanates, aldehydes, alkali metals, nitrides, hydrides, and other strong reducing agents. Reactions with these materials generate heat and in many cases hydrogen gas. Liberates hydrogen sulfide upon reaction with acids
Waste Disposal
Dissolve or mix the material with a combustible solvent and burn in a chemical incinerator equipped with an afterburner and scrubber. All federal, state, and local environmental regulations must be observed.
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Thiophosgene Preparation Products And Raw materials
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Raw materials
Preparation Products
Fluorescein isothiocyanate isomer I-->5-ISOTHIOCYANATO-1,3-DIMETHYL-1H-PYRAZOLE-->2-(1,3-DIMETHYL-1H-PYRAZOL-5-YL)ETHENETHIONE-->3-ISOTHIOCYANATO-1,5-DIMETHYL-1H-PYRAZOLE-->2-ISOTHIOCYANATO-4,6-DIMETHOXYPYRIMIDINE-->5-BROMO-6-ISOTHIOCYANATE QUINOXALINE-->3,4-METHYLENEDIOXYPHENYL ISOTHIOCYANATE-->Amoscanate-->4-(1H-PYRAZOL-1-YL)PHENYL ISOTHIOCYANATE-->4-phenoxy-2，6-diisopropyl phenyl isothiocyanate-->1,4-PHENYLENE DIISOTHIOCYANATE-->DI-2-PYRIDYL THIONOCARBONATE-->4-CARBOXYPHENYL ISOTHIOCYANATE-->3-CHLORO-2-METHYLPHENYL ISOTHIOCYANATE-->2-ETHOXYPHENYL ISOTHIOCYANATE-->2,3-DIHYDRO-1,4-BENZODIOXIN-6-YL ISOTHIOCYANATE-->3,5-DIMETHYLPHENYL ISOTHIOCYANATE-->2-CHLORO-4-METHYLPHENYL ISOTHIOCYANATE-->4-CHLORO-2-METHYLPHENYL ISOTHIOCYANATE-->3,5-DIMETHOXYPHENYL ISOTHIOCYANATE
Company Profile Introduction
Henan CoreyChem Co., Ltd, based on the original Zhengzhou Cote Chemical Research Institute, be brave in absorbing highly educated talents & overseas returnees; actively responded to Zhengzhou City High-tech Zone Government’s Special Care Policy, reorganized and founded in National University of Science and Technology Park, which is a high-tech, stock enterprise of high-end chemical Custom synthesis;The park was created by the People's Government of Henan Province, and proved by Ministry of Education and the National Science & Technology, taking the construction mode of "many college a park, and common development", mainly depends on Zhengzhou University and Henan University’s scientific research and talent advantage to set up Universities, scientific research institute and enterprise scientific research achievements transformation platform, to make high-tech enterprises incubate, is the new high-tech talent gathering base, high and new technology industry enterprise radiation base, colleges and universities technological innovation base.
Henan Coreychem Co., Ltd, facing global High-tech pharmaceutical raw materials, high complex new type intermediates, fine chemicals custom synthesis, scale-up production and Rare chemicals trade. Corey have well-equipped machine, strong technical force and considerate marketing team service. We also have rich experience advantage in basic research, small scale process development, scale-up, industrial technology development & production and cost control.
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- 2024-09-23
- Since:2014-12-17
- Address: No.967,15th Floor,Unit 7, Building 1, No.70 of DianChang Road, High-tech Development Zone, Zhengzho
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