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Triethyl phosphate
Triethyl phosphate

Triethyl phosphate

Price USD2.00
Packge 1kg
  • Min. Order:1kg
  • Supply Ability:ask
  • Time:2019-07-06

Product Details

  • Product NameTriethyl phosphate
  • CAS No.78-40-0
  • EINECS No.201-114-5
  • MFC6H15O4P
  • MW182.15
  • InChIKeyDQWPFSLDHJDLRL-UHFFFAOYSA-N
  • AppearanceLiquidClear
  • Boiling point 215 °C (lit.)
  • density 1.072 g/mL at 25 °C (lit.)
  • Melting point -56 °C
  • Water Solubility SOLUBLE
  • storage temp. Store below +30°C.
Triethyl phosphate Basic information
Product Name: Triethyl phosphate
Synonyms: TRIETHYL PHOSPHATE;(C2H5O)3PO;Ethyl phosphate ((EtO)3PO);Ethyl phosphate, tri-;o-Phosphoric acid triethyl ester;phosphatedetriethyle;Phosphoric ether;triethoxyphosphineoxide
CAS: 78-40-0
MF: C6H15O4P
MW: 182.15
EINECS: 201-114-5
Product Categories: Organics;Functional Materials;Phosphates (Plasticizer);Plasticizer;organophosphorus compound;auxiliary antioxidizer of fire retardant;Building Blocks;Chemical Synthesis;Organic Building Blocks;Organic Phosphates/Phosphites;Phosphorus Compounds;solvent
Mol File: 78-40-0.mol
Triethyl phosphate Structure
 
Triethyl phosphate Chemical Properties
Melting point  -56 °C
Boiling point  215 °C(lit.)
density  1.072 g/mL at 25 °C(lit.)
vapor density  6.28 (vs air)
vapor pressure  1 mm Hg ( 40 °C)
refractive index  n20/D 1.403(lit.)
Fp  240 °F
storage temp.  Store below +30°C.
solubility  500g/l (slow decomposition)
form  Liquid
color  Clear
PH 7 (H2O, 20℃)
explosive limit 1.2-10%(V)
Water Solubility  SOLUBLE
Merck  14,9674
Stability: Stable. Combustible. Incompatible with strong oxidizing agents, water.
InChIKey DQWPFSLDHJDLRL-UHFFFAOYSA-N
CAS DataBase Reference 78-40-0(CAS DataBase Reference)
NIST Chemistry Reference Triethyl phosphate(78-40-0)
EPA Substance Registry System Phosphoric acid, triethyl ester(78-40-0)
 
Safety Information
Hazard Codes  Xn
Risk Statements  22-36
Safety Statements  25-26
RIDADR  3278
WGK Germany  1
RTECS  TC7900000
TSCA  Yes
HS Code  29190090
Hazardous Substances Data 78-40-0(Hazardous Substances Data)
MSDS Information
Provider Language
Triethyl phosphate English
SigmaAldrich English
ACROS English
ALFA English
 
Triethyl phosphate Usage And Synthesis
Chemical Properties Colorless, high-boiling liquid; mild odor. Very stable at ordinary temperatures, compatible with many gums and resins, soluble in most organic solvents, miscible with water. When mixed with water is quite stable at room temperature, but at elevated temperatures it hydrolyzes slowly. Combustible.
Definition ChEBI: A trialkyl phosphate that is the triethy ester derivative of phosphoric acid.
Uses As ethylating agent; formation of polyesters which are used as insecticides.
General Description A colorless, corrosive liquid. Combustible. Slowly dissolves in water and sinks in water. Severely irritates skin, eyes and mucous membranes.
Air & Water Reactions Slowly dissolves in water with slight decomposition .
Reactivity Profile Organophosphates, such as Triethyl phosphate, are susceptible to formation of highly toxic and flammable phosphine gas in the presence of strong reducing agents such as hydrides. Partial oxidation by oxidizing agents may result in the release of toxic phosphorus oxides.
Health Hazard May be harmful by inhalation, ingestion or absorption. May cause irritation.
Fire Hazard Special Hazards of Combustion Products: May produce hazardous decomposition products such as carbon dioxide, carbon monoxide and oxides of phosphorus.
Safety Profile Moderately toxic by ingestion, intraperitoneal, and intravenous routes. Experimental reproductive effects. Mutation data reported. Causes cholinesterase inhibition, but to a lesser extent than parathion. May be expected to cause nerve injury similar to that of other phosphate esters. Combustible when exposed to heat or flame. Can react vigorously with oxidizing materials. To fight fire, use CO2, dry chemical, alcohol foam. When heated to decomposition it emits toxic fumes of POx. See also PARATHION.
Purification Methods Dry the ester by refluxing it with solid BaO and then fractionally distil it under reduced pressure. It is kept over Na and distilled. Store it in the receiver protected from light and moisture. Alternatively it is dried over Na2SO4 and distilled under reduced pressure. The middle fraction is stirred for several weeks over anhydrous Na2SO4 and again fractionated under reduced pressure until the specific conductance reaches a constant low value of 25 1.19 x 108, 40 1.68 x 108, and 55 2.89 x 108 ohm-1 cm. It has also been fractionated carefully under reduced pressure through a glass helices-packed column. It is soluble in EtOH, Et2O and H2O (dec). [Estok & Wendlandt J Am Chem Soc 77 4767 1955, Hoffmann et al. J Am Chem Soc 78 6413 1956, (P NMR) Muller et al. J Am Chem Soc 78 3557 1956, French et al. J Chem Soc 3582 1959, IR: Bellamy & Beecher J Chem Soc 475 1952 and McIvor Can J Chem 36 820 1958, Kosolapoff Organophosphorus Compounds, Wiley p 258 1950, Beilstein 1 IV 1339.]
 
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Company Profile Introduction

Henan CoreyChem Co., Ltd, based on the original Zhengzhou Cote Chemical Research Institute, be brave in absorbing highly educated talents & overseas returnees; actively responded to Zhengzhou City High-tech Zone Government’s Special Care Policy, reorganized and founded in National University of Science and Technology Park, which is a high-tech, stock enterprise of high-end chemical Custom synthesis;The park was created by the People's Government of Henan Province, and proved by Ministry of Education and the National Science & Technology, taking the construction mode of "many college a park, and common development", mainly depends on Zhengzhou University and Henan University’s scientific research and talent advantage to set up Universities, scientific research institute and enterprise scientific research achievements transformation platform, to make high-tech enterprises incubate,  is the new high-tech talent gathering base, high and new technology industry enterprise radiation base, colleges and universities technological innovation base.
 
Henan Coreychem Co., Ltd, facing global High-tech pharmaceutical raw materials, high complex new type intermediates, fine chemicals custom synthesis, scale-up production and Rare chemicals trade. Corey have well-equipped machine, strong technical force and considerate marketing team service. We also have rich experience advantage in basic research, small scale process development, scale-up, industrial technology development & production and cost control.
 

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  • Since:2014-12-17
  • Address: No.967,15th Floor,Unit 7, Building 1, No.70 of DianChang Road, High-tech Development Zone, Zhengzho
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