1-Hexanol
| Price | USD1.00 |
| Packge | 1kg |
- Min. Order:1 g
- Supply Ability:100KG
- Time:2019-07-06
Product Details
- Product Name1-Hexanol
- CAS No.111-27-3
- EINECS No.203-852-3
- MFC6H14O
- MW102.17
- InChIKeyZSIAUFGUXNUGDI-UHFFFAOYSA-N
- AppearanceLiquidClear colorless
- Melting point -52 °C (lit.)
- Boiling point 156-157 °C (lit.)
- Water Solubility 6 g/L (25 ºC)
- density 0.814 g/mL at 25 °C (lit.)
- storage temp. no restrictions.
AD68
| 1-Hexanol Basic information |
| Product Name: | 1-Hexanol |
| Synonyms: | 1-Hexyl alcohol;1-Hexylalcohol;alcooln-hexylique;Capronicalcohol;Caproyl alcohol;caproylalcohol;Epal 6;epal6 |
| CAS: | 111-27-3 |
| MF: | C6H14O |
| MW: | 102.17 |
| EINECS: | 203-852-3 |
| Product Categories: | 1-Alkanols;Monofunctional & alpha,omega-Bifunctional Alkanes;Monofunctional Alkanes;Fatty Alcohols;Reagent Grade Solvents;ACS and Reagent Grade Solvents;Amber Glass Bottles;Biochemicals and Reagents;Fatty Acyls;Lipids;Reagent;Solvent Bottles;Solvent by Application;Solvent Packaging Options;Solvents;Allium sativum (Garlic);Melaleuca alternifolia;Anhydrous Solvents;Carthamus tinctorius (Safflower oil);Citrus aurantium (Seville orange);Nutrition Research;Phytochemicals by Plant (Food/Spice/Herb);Sure/Seal Bottles;Zingiber officinale (Ginger);Alcohols;Building Blocks;C2 to C6;Chemical Synthesis;Organic Building Blocks;Oxygen Compounds |
| Mol File: | 111-27-3.mol |
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| 1-Hexanol Chemical Properties |
| Melting point | −52 °C(lit.) |
| Boiling point | 156-157 °C(lit.) |
| density | 0.820 g/mL at 20 °C |
| vapor density | 4.5 (vs air) |
| vapor pressure | 1 mm Hg ( 25.6 °C) |
| refractive index | n20/D 1.418(lit.) |
| FEMA | 2567 | HEXYL ALCOHOL |
| Fp | 140 °F |
| storage temp. | Storage temperature: no restrictions. |
| solubility | ethanol: soluble(lit.) |
| form | Liquid |
| color | Clear colorless |
| Relative polarity | 0.559 |
| explosive limit | 1.2-7.7%(V) |
| Water Solubility | 6 g/L (25 ºC) |
| Merck | 14,4697 |
| BRN | 969167 |
| Stability: | Stable. Substances to be avoided include strong acids, strong oxidizing agents. Combustible. |
| CAS DataBase Reference | 111-27-3(CAS DataBase Reference) |
| NIST Chemistry Reference | 1-Hexanol(111-27-3) |
| EPA Substance Registry System | 1-Hexanol(111-27-3) |
| Safety Information |
| Hazard Codes | Xn |
| Risk Statements | 22 |
| Safety Statements | 24/25 |
| RIDADR | UN 2282 3/PG 3 |
| WGK Germany | 1 |
| RTECS | MQ4025000 |
| TSCA | Yes |
| HazardClass | 3 |
| PackingGroup | III |
| HS Code | 29051900 |
| Hazardous Substances Data | 111-27-3(Hazardous Substances Data) |
| MSDS Information |
| Provider | Language |
|---|---|
| 1-Hexanol | English |
| SigmaAldrich | English |
| ACROS | English |
| ALFA | English |
| 1-Hexanol Usage And Synthesis |
| General Description | Colorless liquid. The boiling point is 157 ° C; the relative density is 0.819. Miscible in ethanol, propylene glycol and oil. There are light blue shoots breath, wine, fruit and fat flavor. Naturally occurs in some fruits such as apples, strawberries, bitter oranges, also found in camphor oil, tea leaves, tobacco leaves, eucalyptus and coffee. It appears as colorless transparent liquid with fruit-like aroma at low concentration. Sweet; rapidly oxidized in the air; can have polymerization reaction upon contact with concentrated inorganic acid. Similar to normal fatty aldehydes, it can be oxidized to caproic acid and reduced to hexanol. |
| Uses |
|
| Content Analysis | Add 700 ml of newly distilled pyridine into a 1000 ml brown bottle with a glass stopper; add phthalic anhydride 11 5g with strong shaking to complete dissolution. Take the solution 25.0ml, adding into a bottle with heat pressure resistance. The bottle are tightly wrapped and fixed.Weigh the sample about 1 g with the weighing pipette; add it into the pressure bottle; stamped. The sample was fixed in a canvas bag, heated in a water bath at 98~100 ℃ for 3h, and let the water level in the water bath higher than the bottle level. After removal, cool it to room temperature; carefully open the stopper, and do not make a content loss. Add 0.5mol/L sodium hydroxide solution 50.0ml (Note: This 50.0ml 0.5mol/L sodium hydroxide solution is not included in the final calculation). Add 1% phenolphthalein 5 drops of pyridine solution, and then 0.5 mol/L sodium hydroxide solution to the pink end point and maintain 15 s unchanged. At the same time carry out a blank test. Per milliliter of sodium hydroxide solution 0.5mol/L is equivalent to alcohol (C6H14O) 51.09 mg. Or measured by non-polar column in GT-10-4 gas chromatography. |
| maximum level | FEMA (mg/kg): soft drinks 6.6; cold drinks 26; candy 21; baked food 18; puddings 0.22 to 0.28. Moderation (FDA § 172.515, 2000). |
| Preparation |
|
| Production methods | (1) It is generally derived from acetic acid reduction in industry. Bromine butane and magnesium shards reaction obtains butyl magnesium bromide, and the butyl magnesium bromide reacted with ethylene oxide to get ethanol under laboratorial study. (2) Via n-hexylic acid reduction. |
| Hazards & Safety Information | Category: Flammable liquids Toxic classification: Moderately hazardous Acute toxicity Oral-Rat LD50: 720 mg/kg; Oral-mouse LD50: 1950 mg/kg Stimulation data: Skin-Rabbit 10 mg/24 h Mild; Eye-Rabbit 250 μg Severity. Flammability characteristics: In case of fire, high temperature, strong oxidant flammable; combustion emissions to stimulate smoke Storage and transport: Packaging integrity, light loading and unloading; Treasury ventilation, away from open flame, high temperature, stored separately from the oxidant. Fire extinguishing agent: Foam, dry powder, carbon dioxide, sand. |
| Chemical Properties | Colourless liquid (odour recognition threshold 0.09ppm) |
| Uses | 1-Hexanol was examined as a perturbing agent on actomyosin ATPase and and was found to modulate the function of actomyosin motor via intermediate-specific structural perturbation. |
| Definition | ChEBI: A primary alcohol that is hexane substituted by a hydroxy group at position 1. |
| Hazard | Combustible. |
| Purification Methods | The commercial material usually contains other alcohols which are difficult to remove. A suitable method is to esterify with hydroxybenzoic acid, recrystallise the ester and saponify. [Olivier Recl Trav Chim, Pays-Bas 55 1027 1936.] Drying agents include K2CO3 and CaSO4, followed by filtration and distillation. (Some decomposition to the olefin occurs when Al amalgam is used as drying agent at room temperature, even if the amalgam is removed prior to distillation.) If the alcohol is required anhydrous, the redistilled material can be refluxed with the appropriate alkyl phthalate or succinate, as described under Ethanol. [Beilstein 1 IV 1694.] |
Company Profile Introduction
Henan CoreyChem Co., Ltd, based on the original Zhengzhou Cote Chemical Research Institute, be brave in absorbing highly educated talents & overseas returnees; actively responded to Zhengzhou City High-tech Zone Government’s Special Care Policy, reorganized and founded in National University of Science and Technology Park, which is a high-tech, stock enterprise of high-end chemical Custom synthesis;The park was created by the People's Government of Henan Province, and proved by Ministry of Education and the National Science & Technology, taking the construction mode of "many college a park, and common development", mainly depends on Zhengzhou University and Henan University’s scientific research and talent advantage to set up Universities, scientific research institute and enterprise scientific research achievements transformation platform, to make high-tech enterprises incubate, is the new high-tech talent gathering base, high and new technology industry enterprise radiation base, colleges and universities technological innovation base.
Henan Coreychem Co., Ltd, facing global High-tech pharmaceutical raw materials, high complex new type intermediates, fine chemicals custom synthesis, scale-up production and Rare chemicals trade. Corey have well-equipped machine, strong technical force and considerate marketing team service. We also have rich experience advantage in basic research, small scale process development, scale-up, industrial technology development & production and cost control.
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