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Homecompany1,1'-Bis(diphenylphosphino)ferrocene
1,1'-Bis(diphenylphosphino)ferrocene
1,1'-Bis(diphenylphosphino)ferrocene
1,1'-Bis(diphenylphosphino)ferrocene

1,1'-Bis(diphenylphosphino)ferrocene

Price USD1.00
Packge 1KG
  • Min. Order:1KG
  • Supply Ability:1000KG
  • Time:2019-07-06

Product Details

  • Product Name1,1'-Bis(diphenylphosphino)ferrocene
  • CAS No.12150-46-8
  • EINECS No.430-420-3
  • MFC34H28FeP210*
  • MW554.38
  • Appearancecrystalyellow to orange
  • Melting point 181-182 °C (dec.)(lit.)
  • storage temp. 2-8°C
  • Water Solubility Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.

AD68

1,1'-Bis(diphenylphosphino)ferrocene Basic information
Reaction
Product Name: 1,1'-Bis(diphenylphosphino)ferrocene
Synonyms: DPPF;1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE;1,1'-FERROCENEDIYL-BIS(DIPHENYLPHOSPHINE);1,1'-FERROCENEBIS(DIPHENYLPHOSPHINE);1,1'-bis(diphenyphosphino)ferrocene;1,1'-bis(diphenyphosphino)ferrocene(dppf);1,1'-BIS(DIPHENYLPHOSPHINO)FERROCENE, 97 %;1,1'-Bis(diphenylphosphino)ferrocene,99%DPPF
CAS: 12150-46-8
MF: C34H28FeP2 10*
MW: 554.38
EINECS: 430-420-3
Product Categories: Phosphines;Boron, Nitrile, Thio,& TM-Cpds;Miscellaneous;pharmacetical;Ligand;Catalysts-Ligands;Classes of Metal Compounds;Fe (Iron) Compounds;Ferrocenes;Metallocenes;Phosphine Ligands;Synthetic Organic Chemistry;Transition Metal Compounds;Aromatics;Catalyst;Chelating Agents & Ligands;Pharmaceutical intermediates;Achiral Phosphine;Aryl Phosphine
Mol File: 12150-46-8.mol
1,1'-Bis(diphenylphosphino)ferrocene Structure
 
1,1'-Bis(diphenylphosphino)ferrocene Chemical Properties
Melting point  181-182 °C (dec.)(lit.)
storage temp.  2-8°C
form  crystal
color  yellow to orange
Water Solubility  Soluble in chloroform, dichloromethane, alcohol and pentane. Insoluble in water.
Sensitive  Air Sensitive
Stability: Stable. Incompatible with strong oxidizing agents.
CAS DataBase Reference 12150-46-8(CAS DataBase Reference)
NIST Chemistry Reference 1,1'-Bis(diphenylphosphino)ferrocene(12150-46-8)
 
Safety Information
Hazard Codes  T,Xi,Xn
Risk Statements  25-36/37/38-20/21/22
Safety Statements  22-24/25-45-28A-36-26-36/37/39
RIDADR  3467
WGK Germany  3
F  10-23
TSCA  No
HazardClass  IRRITANT
HS Code  29319090
 
 
1,1'-Bis(diphenylphosphino)ferrocene Usage And Synthesis
Reaction
  1. Ligand for Pd-catalyzed cross-coupling.
  2. Useful ligand for Pd-catalyzed carbon-nitrogen and carbon-oxygen bond forming procedures.
  3. Ligand for Ni-catalyzed amination of aryl chlorides.
  4. Ligand for Pd-catalyzed conversion of aryl halides to aryl nitriles.
  5. Ligand for Ni-catalyzed Suzuki reactions.
  6. Ni-catalyzed hydroamination of 1,3-dienes.
  7. Pd-catalyzed hydrocarbonation and hydroamination of 3,3-dihexylcyclopropene.
  8. Pd-catalyzed γ-arylation of β,γ-unsaturated ketones.
  9. Ligand for Ru-catalyzed reduction of nitriles to primary amines.
  10. Ligand for Rh-catalyzed alkyne head-to-tail dimerization.
  11. Ligand for Rh-catalyzed cross-coupling
  12. Ligand for Rh-catalyzed olefin isomerization
  13. Ligand for Ni or Rh-catalyzed borylation
  14. Ligand for regioselective Pd-catalyzed hydrophosphinylation of terminal alkynes to form branched alkenes.
Chemical Properties deep yellow crystalline powder
Uses suzuki reaction
Uses Commonly used coordination compound in synthesis, readily forms complexes with various metals, i.e. when reacting with the acetonitrile or benzonitrile complexes of PdCl2 it forms (dppf)PdCl2, which i s a popular reagent for palladium-catalyzed coupling reactions.

Company Profile Introduction

Henan CoreyChem Co., Ltd, based on the original Zhengzhou Cote Chemical Research Institute, be brave in absorbing highly educated talents & overseas returnees; actively responded to Zhengzhou City High-tech Zone Government’s Special Care Policy, reorganized and founded in National University of Science and Technology Park, which is a high-tech, stock enterprise of high-end chemical Custom synthesis;The park was created by the People's Government of Henan Province, and proved by Ministry of Education and the National Science & Technology, taking the construction mode of "many college a park, and common development", mainly depends on Zhengzhou University and Henan University’s scientific research and talent advantage to set up Universities, scientific research institute and enterprise scientific research achievements transformation platform, to make high-tech enterprises incubate,  is the new high-tech talent gathering base, high and new technology industry enterprise radiation base, colleges and universities technological innovation base.
 
Henan Coreychem Co., Ltd, facing global High-tech pharmaceutical raw materials, high complex new type intermediates, fine chemicals custom synthesis, scale-up production and Rare chemicals trade. Corey have well-equipped machine, strong technical force and considerate marketing team service. We also have rich experience advantage in basic research, small scale process development, scale-up, industrial technology development & production and cost control.
 

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career henan chemical co

Henan China
  • Since:2014-12-17
  • Address: No.967,15th Floor,Unit 7, Building 1, No.70 of DianChang Road, High-tech Development Zone, Zhengzho
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