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1918-00-9

1918-00-9 structural image
Product Name: Dicamba
Formula: C8H6Cl2O3
Synonyms: 3,6-Dichloro-o-anisic acid;3,6-Dichloro-2-methoxybenzoic acid
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Dicamba is a white solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Since it is a liquid it can easily penetrate the soil and contaminate groundwater and nearby streams. It can cause illness by inhalation, skin absorption and/or ingestion. It is used as a herbicide.
Color/Form Crystals from pentane
Odor Odorless (reference grade)
Boiling Point > 200 °C
Melting Point 237.2 to 240.8 °F (USCG, 1999)
Flash Point Not Applicable. Not flammable. (USCG, 1999)
Solubility In water, 8310 mg/L at 25 °C
Density 1.57 g/cu cm at 25 °C
Vapor Density 7.62 (USCG, 1999) - Heavier than air; will sink (Relative to Air)
Vapor Pressure 0.0000338 [mmHg]
LogP log Kow = 2.21
Stability/Shelf Life Stable under recommended storage conditions.
Autoignition Temperature Not Applicable. Not flammable. (USCG, 1999)
Decomposition When heated to decomposition it emits toxic fumes of /chlorine/.
Corrosivity Mild to noncorrosive
Odor Threshold /SRP: Air/ 250.8 PPM
Dissociation Constants pKa = 1.97
Collision Cross Section 157.21 Ų [M+Na]+ [CCS Type: DT, Method: stepped-field]
Kovats Retention Index 1617 1657.6
Other Experimental Properties At 200 °C dicamba is decarboxylated to give 2,5-dichloroanisole
Chemical Classes Pesticides -> Herbicides, Chlorophenoxy

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Corrosion
Corrosives
GHS05

Exclamation Mark
Irritant
GHS07
GHS Hazard Statements H302:Acute toxicity,oral
H318:Serious eye damage/eye irritation
H412:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P264:Wash hands thoroughly after handling.
P264:Wash skin thouroughly after handling.
P270:Do not eat, drink or smoke when using this product.
P273:Avoid release to the environment.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 221.03 g/mol
XLogP3 2.2
Hydrogen Bond Donor Count 1
Hydrogen Bond Acceptor Count 3
Rotatable Bond Count 2
Exact Mass 219.9693994 g/mol
Monoisotopic Mass 219.9693994 g/mol
Topological Polar Surface Area 46.5 Ų
Heavy Atom Count 13
Formal Charge 0
Complexity 198
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Dicamba is a white solid dissolved in a liquid carrier. The carrier is water emulsifiable. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. Since it is a liquid it can easily penetrate the soil and contaminate groundwater and nearby streams. It can cause illness by inhalation, skin absorption and/or ingestion. It is used as a herbicide.

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