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15096-52-3

15096-52-3 structural image
Product Name: cryolite
Formula: AlF6Na3
Synonyms: Kryolith;Sodium hexafluoroaluminate
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Sodium aluminum fluoride appears as an odorless white solid or powder. mp: 1291 °C. Density: 2.95 g/cm3. Dust irritates the eyes and skin; inhaled dust irritates the nose, mouth and lungs. Insoluble in water. Synthesized by fusion of sodium fluoride and aluminum fluoride as a electrolyte in the reduction of alumina to aluminum metal. Occurs in nature as the mineral cryolite. Aqueous suspensions of powdered sodium aluminum fluoride are used as insecticides.
Color/Form MONOCLINIC CRYSTALS (NATURAL PRODUCT); AMORPHOUS POWDER (SYNTHETIC PRODUCT)
Odor Odorless.
Boiling Point Decomposes (NIOSH, 2023)
Melting Point 1832 °F (NIOSH, 2023)
Solubility 0.04 % (NIOSH, 2023)
Density 2.9 (NIOSH, 2023) - Denser than water; will sink
Vapor Pressure 0 mmHg (approx) (NIOSH, 2023)
Stability/Shelf Life Low melting solids or colorless, volatile liquids. /Alkylaluminum halides/
Decomposition When heated to decomposition it emits toxic fumes of /fluorides and disodium oxide/.
Heat of Vaporization 225 kJ/mol at 1012 °C
Surface Tension Liquid in air, 125 mN/m (= dyn/cm)
Refractive Index Index of refraction: 1.338
Other Experimental Properties Moh's hardness 2.5-3; fuses fairly easily
Chemical Classes Other Classes -> Fluorides, Inorganic

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Exclamation Mark
Irritant
GHS07

Health Hazard
GHS08

Environment
GHS09
GHS Hazard Statements H332:Acute toxicity,inhalation
H372:Specific target organ toxicity, repeated exposure
H411:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P273:Avoid release to the environment.
P314:Get medical advice/attention if you feel unwell.

COMPUTED DESCRIPTORS

Molecular Weight 209.941265 g/mol
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 7
Rotatable Bond Count 0
Exact Mass 209.9412652 g/mol
Monoisotopic Mass 209.9412652 g/mol
Topological Polar Surface Area 0 Ų
Heavy Atom Count 10
Formal Charge 0
Complexity 62.7
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 4
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Sodium aluminum fluoride appears as an odorless white solid or powder. mp: 1291 °C. Density: 2.95 g/cm3. Dust irritates the eyes and skin; inhaled dust irritates the nose, mouth and lungs. Insoluble in water. Synthesized by fusion of sodium fluoride and aluminum fluoride as a electrolyte in the reduction of alumina to aluminum metal. Occurs in nature as the mineral cryolite. Aqueous suspensions of powdered sodium aluminum fluoride are used as insecticides.

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