15096-52-3
Product Name:
cryolite
Formula:
AlF6Na3
Synonyms:
Kryolith;Sodium hexafluoroaluminate
Inquiry
CHEMICAL AND PHYSICAL PROPERTIES
Physical Description | Sodium aluminum fluoride appears as an odorless white solid or powder. mp: 1291 °C. Density: 2.95 g/cm3. Dust irritates the eyes and skin; inhaled dust irritates the nose, mouth and lungs. Insoluble in water. Synthesized by fusion of sodium fluoride and aluminum fluoride as a electrolyte in the reduction of alumina to aluminum metal. Occurs in nature as the mineral cryolite. Aqueous suspensions of powdered sodium aluminum fluoride are used as insecticides. |
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Color/Form | MONOCLINIC CRYSTALS (NATURAL PRODUCT); AMORPHOUS POWDER (SYNTHETIC PRODUCT) |
Odor | Odorless. |
Boiling Point | Decomposes (NIOSH, 2023) |
Melting Point | 1832 °F (NIOSH, 2023) |
Solubility | 0.04 % (NIOSH, 2023) |
Density | 2.9 (NIOSH, 2023) - Denser than water; will sink |
Vapor Pressure | 0 mmHg (approx) (NIOSH, 2023) |
Stability/Shelf Life | Low melting solids or colorless, volatile liquids. /Alkylaluminum halides/ |
Decomposition | When heated to decomposition it emits toxic fumes of /fluorides and disodium oxide/. |
Heat of Vaporization | 225 kJ/mol at 1012 °C |
Surface Tension | Liquid in air, 125 mN/m (= dyn/cm) |
Refractive Index | Index of refraction: 1.338 |
Other Experimental Properties | Moh's hardness 2.5-3; fuses fairly easily |
Chemical Classes | Other Classes -> Fluorides, Inorganic |
SAFETY INFORMATION
Signal word | Danger |
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Pictogram(s) |
Exclamation Mark Irritant GHS07 Health Hazard GHS08 Environment GHS09 |
GHS Hazard Statements |
H332:Acute toxicity,inhalation H372:Specific target organ toxicity, repeated exposure H411:Hazardous to the aquatic environment, long-term hazard |
Precautionary Statement Codes |
P273:Avoid release to the environment. P314:Get medical advice/attention if you feel unwell. |
COMPUTED DESCRIPTORS
Molecular Weight | 209.941265 g/mol |
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Hydrogen Bond Donor Count | 0 |
Hydrogen Bond Acceptor Count | 7 |
Rotatable Bond Count | 0 |
Exact Mass | 209.9412652 g/mol |
Monoisotopic Mass | 209.9412652 g/mol |
Topological Polar Surface Area | 0 Ų |
Heavy Atom Count | 10 |
Formal Charge | 0 |
Complexity | 62.7 |
Isotope Atom Count | 0 |
Defined Atom Stereocenter Count | 0 |
Undefined Atom Stereocenter Count | 0 |
Defined Bond Stereocenter Count | 0 |
Undefined Bond Stereocenter Count | 0 |
Covalently-Bonded Unit Count | 4 |
Compound Is Canonicalized | Yes |
PRODUCT INTRODUCTION
description
Sodium aluminum fluoride appears as an odorless white solid or powder. mp: 1291 °C. Density: 2.95 g/cm3. Dust irritates the eyes and skin; inhaled dust irritates the nose, mouth and lungs. Insoluble in water. Synthesized by fusion of sodium fluoride and aluminum fluoride as a electrolyte in the reduction of alumina to aluminum metal. Occurs in nature as the mineral cryolite. Aqueous suspensions of powdered sodium aluminum fluoride are used as insecticides.