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1333-82-0

1333-82-0 structural image
Product Name: Chromium(VI) oxide
Formula: CrO3
Synonyms: Chromic anhydride;Chromic anhydride, Chromium trioxide;Chromium(VI) oxide
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Chromium trioxide, anhydrous appears as a dark purplish red solid. Under prolonged exposure to fire or heat the containers may explode. Highly toxic. A confirmed human carcinogen.
Color/Form Dark red, bipyramidal prismatic crystals, flakes or granular powder
Odor Odorless
Boiling Point 482 °F at 760 mmHg (decomposes) (NTP, 1992)
Melting Point 385 °F (NTP, 1992)
Solubility Very soluble (NTP, 1992)
Density 2.7 (NTP, 1992) - Denser than water; will sink
Vapor Pressure Very low (NIOSH, 2023)
Stability/Shelf Life Stable under recommended storage conditions.
Autoignition Temperature May ignite organic materials on contact. (USCG, 1999)
Decomposition Decomposes when heated to 250 °C, liberating oxygen to support combustion.
pH Dissolves in water to form a weak acid
Other Experimental Properties Chromium trioxide, CrO3, contains hexavalent chromium. Its molecular weight is 100.01. It is also known as red oxide of chromium, chromic anhydride, chromic acid anhydride and, erroneously, chromic acid.
Chemical Classes Metals -> Chromium Compounds, Inorganic

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Flame Over Circle
Oxidizers
GHS03

Corrosion
Corrosives
GHS05

Skull and Crossbones
Acute Toxicity
GHS06

Health Hazard
GHS08

Environment
GHS09
GHS Hazard Statements H271:Oxidising liquids;Oxidising solids
H314:Skin corrosion/irritation
H317:Sensitisation, Skin
H330:Acute toxicity,inhalation
H334:Sensitisation, respiratory
H335:Specific target organ toxicity, single exposure;Respiratory tract irritation
H340:Germ cell mutagenicity
H350:Carcinogenicity
H372:Specific target organ toxicity, repeated exposure
H410:Hazardous to the aquatic environment, long-term hazard
Precautionary Statement Codes P210:Keep away from heat/sparks/open flames/hot surfaces. — No smoking.
P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 99.994 g/mol
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 3
Rotatable Bond Count 0
Exact Mass 99.925249 g/mol
Monoisotopic Mass 99.925249 g/mol
Topological Polar Surface Area 51.2 Ų
Heavy Atom Count 4
Formal Charge 0
Complexity 61.8
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Chromium trioxide, anhydrous appears as a dark purplish red solid. Under prolonged exposure to fire or heat the containers may explode. Highly toxic. A confirmed human carcinogen.

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