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10026-13-8

10026-13-8 structural image
Product Name: Phosphorus pentachloride
Formula: Cl5P
Synonyms: Phosphorus pentachloride;Phosphorus(V) chloride;Phosphorus(V) chloride, polymer-bound
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Phosphorus pentachloride is a greenish-yellow crystalline solid with an irritating odor. It is decomposed by water to form hydrochloric and phosphoric acid and heat. This heat may be sufficient to ignite surrounding combustible material. It is corrosive to metals and tissue. Long term exposure to low concentrations or short term exposure to high concentrations can result in adverse health effects from inhalation.
Color/Form White to pale yellow crystalline mass
Odor Pungent, unpleasant odor
Boiling Point 320 °F at 760 mmHg (EPA, 1998)
Melting Point (decomposes) 298 °F (under pressure) sublimes at about 212 °F without melting (EPA, 1998)
Solubility Reacts with water (NIOSH, 2023)
Density 3.6 (NIOSH, 2023) - Denser than water; will sink
Vapor Density 7.2 (Air = 1)
Vapor Pressure 1 mmHg at 131.9 °F (EPA, 1998)
Decomposition PRODUCES PHOSPHORUS TRICHLORIDE & CHLORINE WHEN HEATED; PRODUCES PHOSPHORUS OXYCHLORIDE, PHOSPHORIC ACID, & HYDROCHLORIC ACID WHEN DECOMPOSED IN WATER
Corrosivity Corrosive
Heat of Vaporization 64.9 kJ/mol
Other Experimental Properties Deliquescent; reacts with alcohols to form corresponding chloride
Chemical Classes Toxic Gases & Vapors -> Other Toxic Gases & Vapors

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Corrosion
Corrosives
GHS05

Skull and Crossbones
Acute Toxicity
GHS06

Health Hazard
GHS08
GHS Hazard Statements H302:Acute toxicity,oral
H314:Skin corrosion/irritation
H330:Acute toxicity,inhalation
H373:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P260:Do not breathe dust/fume/gas/mist/vapours/spray.
P280:Wear protective gloves/protective clothing/eye protection/face protection.
P314:Get medical advice/attention if you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 208.2 g/mol
XLogP3 3.9
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 0
Rotatable Bond Count 0
Exact Mass 207.815075 g/mol
Monoisotopic Mass 205.818025 g/mol
Topological Polar Surface Area 0 Ų
Heavy Atom Count 6
Formal Charge 0
Complexity 37.1
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Phosphorus pentachloride is a greenish-yellow crystalline solid with an irritating odor. It is decomposed by water to form hydrochloric and phosphoric acid and heat. This heat may be sufficient to ignite surrounding combustible material. It is corrosive to metals and tissue. Long term exposure to low concentrations or short term exposure to high concentrations can result in adverse health effects from inhalation.

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