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10025-87-3

10025-87-3 structural image
Product Name: Phosphorus oxychloride
Formula: Cl3OP
Synonyms: Phosphorus(V) oxide chloride;Phosphoryl chloride
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CHEMICAL AND PHYSICAL PROPERTIES

Physical Description Phosphorus oxychloride appears as a colorless fuming liquid with a pungent odor. Density 14.0 lb / gal. Very toxic by inhalation and corrosive to metals and tissue. Used in gasoline additives and hydraulic fluids.
Color/Form Clear, colorless to yellow, oily liquid [Note: A solid below 34 degrees F].
Odor Pungent & musty odor
Boiling Point 223 °F at 760 mmHg (EPA, 1998)
Melting Point 34.2 °F (EPA, 1998)
Flash Point Not Flammable (EPA, 1998)
Solubility Decomposes (NIOSH, 2023)
Density 1.645 at 77 °F (EPA, 1998) - Denser than water; will sink
Vapor Density 5.3 (EPA, 1998) - Heavier than air; will sink (Relative to Air)
Vapor Pressure 40 mmHg at 81.14 °F (EPA, 1998)
Autoignition Temperature Not flammable (USCG, 1999)
Decomposition WHEN HEATED TO DECOMPOSITION, IT EMITS HIGHLY TOXIC FUMES OF CHLORIDES AND PO(X).
Corrosivity PRODUCTS OF ITS REACTION WITH WATER RAPIDLY CORRODE STEEL & MOST METALS
Heat of Vaporization 97 BTU/LB= 54 CAL/G= 2.3X10+5 JOULES/KG
Refractive Index Index of refraction: 1.460 at 25 °C/D
Other Experimental Properties Heat of formation = -597.1 kJ/mol
Chemical Classes Toxic Gases & Vapors -> Acid Halides

SAFETY INFORMATION

Signal word Danger
Pictogram(s)

Corrosion
Corrosives
GHS05

Skull and Crossbones
Acute Toxicity
GHS06

Health Hazard
GHS08
GHS Hazard Statements H302:Acute toxicity,oral
H314:Skin corrosion/irritation
H330:Acute toxicity,inhalation
H372:Specific target organ toxicity, repeated exposure
Precautionary Statement Codes P280:Wear protective gloves/protective clothing/eye protection/face protection.
P314:Get medical advice/attention if you feel unwell.
P301+P312:IF SWALLOWED: call a POISON CENTER or doctor/physician IF you feel unwell.
P303+P361+P353:IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338:IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.

COMPUTED DESCRIPTORS

Molecular Weight 153.33 g/mol
XLogP3 1.7
Hydrogen Bond Donor Count 0
Hydrogen Bond Acceptor Count 1
Rotatable Bond Count 0
Exact Mass 151.875235 g/mol
Monoisotopic Mass 151.875235 g/mol
Topological Polar Surface Area 17.1 Ų
Heavy Atom Count 5
Formal Charge 0
Complexity 53
Isotope Atom Count 0
Defined Atom Stereocenter Count 0
Undefined Atom Stereocenter Count 0
Defined Bond Stereocenter Count 0
Undefined Bond Stereocenter Count 0
Covalently-Bonded Unit Count 1
Compound Is Canonicalized Yes

PRODUCT INTRODUCTION

description

Phosphorus oxychloride appears as a colorless fuming liquid with a pungent odor. Density 14.0 lb / gal. Very toxic by inhalation and corrosive to metals and tissue. Used in gasoline additives and hydraulic fluids.

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